Dawei Zhuang, Yanxia Du, Le Chen, Chunming Pu, Qian Zhao, Shaojie Gu
{"title":"利用远地混合电位估算铜/钢耦合的电化学腐蚀率","authors":"Dawei Zhuang, Yanxia Du, Le Chen, Chunming Pu, Qian Zhao, Shaojie Gu","doi":"10.1002/maco.202314006","DOIUrl":null,"url":null,"abstract":"<p>Copper and steel are often electrically connected in industrial devices, which causes galvanic corrosion in environments. To ensure the safety of the devices, it is needed to assess the corrosion rate of galvanic couples. The galvanic current is often used to calculate the galvanic corrosion rate in theory, however, in the actual devices, the copper parts are generally coupled with the steel parts and it is difficult to separate them to measure the galvanic current between them, as well as to determine the galvanic corrosion rates for actual devices. In this paper, the galvanic couple mixed potential distribution and influencing factors including area ratios, polarization characteristics, and medium resistivity are studied by experiments and calculation. The mixed potential becomes stable with a certain distance from the surface of copper/steel couple and acts as remote earth mixed potential. Remote earth mixed potential is positively associated with galvanic corrosion rate. Based on the results of experiments and calculation, a method to estimate the galvanic corrosion rate of steel in copper/steel couple by using the remote earth mixed potential is proposed.</p>","PeriodicalId":18225,"journal":{"name":"Materials and Corrosion-werkstoffe Und Korrosion","volume":"75 5","pages":"636-650"},"PeriodicalIF":1.6000,"publicationDate":"2024-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Estimating galvanic corrosion rate of copper/steel couple by using remote earth mixed potential\",\"authors\":\"Dawei Zhuang, Yanxia Du, Le Chen, Chunming Pu, Qian Zhao, Shaojie Gu\",\"doi\":\"10.1002/maco.202314006\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Copper and steel are often electrically connected in industrial devices, which causes galvanic corrosion in environments. To ensure the safety of the devices, it is needed to assess the corrosion rate of galvanic couples. The galvanic current is often used to calculate the galvanic corrosion rate in theory, however, in the actual devices, the copper parts are generally coupled with the steel parts and it is difficult to separate them to measure the galvanic current between them, as well as to determine the galvanic corrosion rates for actual devices. In this paper, the galvanic couple mixed potential distribution and influencing factors including area ratios, polarization characteristics, and medium resistivity are studied by experiments and calculation. The mixed potential becomes stable with a certain distance from the surface of copper/steel couple and acts as remote earth mixed potential. Remote earth mixed potential is positively associated with galvanic corrosion rate. Based on the results of experiments and calculation, a method to estimate the galvanic corrosion rate of steel in copper/steel couple by using the remote earth mixed potential is proposed.</p>\",\"PeriodicalId\":18225,\"journal\":{\"name\":\"Materials and Corrosion-werkstoffe Und Korrosion\",\"volume\":\"75 5\",\"pages\":\"636-650\"},\"PeriodicalIF\":1.6000,\"publicationDate\":\"2024-01-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials and Corrosion-werkstoffe Und Korrosion\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/maco.202314006\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials and Corrosion-werkstoffe Und Korrosion","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/maco.202314006","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Estimating galvanic corrosion rate of copper/steel couple by using remote earth mixed potential
Copper and steel are often electrically connected in industrial devices, which causes galvanic corrosion in environments. To ensure the safety of the devices, it is needed to assess the corrosion rate of galvanic couples. The galvanic current is often used to calculate the galvanic corrosion rate in theory, however, in the actual devices, the copper parts are generally coupled with the steel parts and it is difficult to separate them to measure the galvanic current between them, as well as to determine the galvanic corrosion rates for actual devices. In this paper, the galvanic couple mixed potential distribution and influencing factors including area ratios, polarization characteristics, and medium resistivity are studied by experiments and calculation. The mixed potential becomes stable with a certain distance from the surface of copper/steel couple and acts as remote earth mixed potential. Remote earth mixed potential is positively associated with galvanic corrosion rate. Based on the results of experiments and calculation, a method to estimate the galvanic corrosion rate of steel in copper/steel couple by using the remote earth mixed potential is proposed.
期刊介绍:
Materials and Corrosion is the leading European journal in its field, providing rapid and comprehensive coverage of the subject and specifically highlighting the increasing importance of corrosion research and prevention.
Several sections exclusive to Materials and Corrosion bring you closer to the current events in the field of corrosion research and add to the impact this journal can make on your work.