电化学的贡献路德维希-蒙德(1839-1909)

IF 2.9 Q2 ELECTROCHEMISTRY Electrochemical science advances Pub Date : 2024-01-12 DOI:10.1002/elsa.202400002
Evgeny Katz
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摘要

燃料电池的一般概念源于英国物理学家威廉-格罗夫的实验,他于 1839 年发表了燃料电池的首批研究成果。他将氢气和氧气分别作为燃料和氧化剂,在铂催化电极上发生反应并产生电能。然而,他的研究仅被认为是对水电解反向过程的科学证明,并无实际意义。事实上,格罗夫发明的电池在短时间内产生的电流和电压非常小。19 世纪 80 年代末,两位英国化学家路德维希-蒙德和他的助手卡尔-朗格(图 1)通过改进催化电极和流道的几何形状,开发出一种使用寿命更长的燃料电池(图 2)。他们采用了格鲁夫电池的已知科学概念,但改进了工程设计。他们的燃料电池可产生每平方英尺 6 安培的电流密度和 730 毫伏的电压。该电池使用煤制气作为燃料,空气(实际上是空气中的氧)作为氧化剂。电池中充满了稀硫酸,包括用多孔非导电膜隔开的薄穿孔铂电极。第一个工程燃料电池于 1889 年展示并获得专利。请注意,路德维希-蒙德(Ludwig Mond)和卡尔-朗格(Carl Langer)是第一个提出 "燃料电池 "一词的人,该词现在已被普遍使用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Electrochemical contributions: Ludwig Mond (1839−1909)

The general concept of fuel cells starts from the experiments of British physicist William Grove who published the first results on fuel cells in 1839. He used hydrogen and oxygen as a fuel and oxidizer, respectively, reacting on platinum catalytic electrodes and generating electric power. However, his research was considered only as scientific proof of the process reversed to the water electrolysis with no practical importance. Indeed, the cell invented by Grove produced a very small current and voltage over a short time. Obviously, after the concept demonstration, some engineering had to be done for improving the cell efficiency to make it feasible for practical use.

During the late 1880s, two British chemists, Ludwig Mond and his assistant Carl Langer (Figure 1), developed a fuel cell with a longer service life with improved geometry of the catalytic electrodes and flow channels (Figure 2). They used the known scientific concept from Grove's cell, but with the improved engineering. Their fuel cell generated 6 amps per square foot current density and 730 mV voltage. The cell operated with coal-derived gas as a fuel and air (actually oxygen in the air) as an oxidizer. The cell was filled with diluted sulfuric acid and included thin perforated platinum electrodes separated with a porous nonconducting membrane. The first engineered fuel cell was demonstrated and patented in 1889. Note that Ludwig Mond and Carl Langer were the first to introduce the term “fuel cell” which is commonly used now.

The author declares that he has no conflict of interest.

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