沸石咪唑酸框架/氧化石墨烯综述:纳米技术中多方面应用的合成、特性和功能协同作用

IF 5.9 3区 材料科学 Q2 CHEMISTRY, PHYSICAL FlatChem Pub Date : 2024-01-24 DOI:10.1016/j.flatc.2024.100618
Negar Sadegh , Iman Mohammadi Dehcheshmeh , Fatemeh Sadegh
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引用次数: 0

摘要

唑基咪唑酸框架/氧化石墨烯(ZIF/GO)混合材料因其结构和功能的智能集成而在纳米技术领域受到关注。本综述探讨了 ZIF 与 GO 作为混合材料的协同组合,为多方面的应用提供了更强的性能。ZIFs 由金属离子与咪唑链节配位而成,其自组装提供了高度有序的多孔框架,而 GO 源自氧化石墨烯片,具有高表面积和机械强度。ZIF 与 GO 的结合可实现孔隙率的可调、导电性的改善和稳定性的提高。本综述讨论了制造 ZIF/GO 混合材料所采用的合成策略,如原位生长、溶热和水热法、超声和纳米孔光刻法。报告阐明了 ZIF/GO 混合物的物理性质和化学特性,包括结构特征、形态特征、热稳定性、导电性、电化学性能和机械行为。此外,报告还探讨了 ZIF/GO 混合材料在催化、能量存储和传输以及生物医学应用方面的各种应用。书中探讨了与 ZIF/GO 混合材料相关的挑战和限制,包括制造问题、稳定性问题、选择性优化和性能提升。这篇全面的综述强调了 ZIF/GO 混合材料在纳米技术多方面应用中的巨大潜力,为研究人员提供了宝贵的见解,并为该领域的未来发展铺平了道路。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Review of zeolitic imidazolate framework/graphene oxide: A synergy of synthesis, properties and function for multifaceted applications in nanotechnology

Zeolitic imidazolate framework/graphene oxide (ZIF/GO) hybrid materials are taken into consideration in the field of nanotechnology due to their intelligent integration of structure and function. This comprehensive review explores the synergistic combination of ZIFs and GO as a hybrid material, offering enhanced properties for multifaceted applications. The self-assembly of ZIFs, composed of metal ions coordinated with imidazolate linkers, provides a highly ordered porous framework, while GO, derived from oxidized graphene sheets, exhibits high surface area and mechanical strength. The integration of ZIFs and GO results in tunable porosity, improved electrical conductivity, and increased stability. This review discusses the synthesis strategies employed for fabricating ZIF/GO hybrids, such as in situ growth, solvothermal and hydrothermal methods, ultrasound, and nanopore lithography approaches. It elucidates the physical properties and chemical properties of ZIF/GO hybrids, encompassing structural characteristics, morphological features, thermal stability, electrical conductivity, electrochemical performance, and mechanical behavior. Furthermore, it explores the diverse applications of ZIF/GO hybrid materials in catalysis, energy storage, and transfer, as well as biomedical applications. The challenges and limitations associated with ZIF/GO hybrids are addressed, encompassing fabrication issues, stability concerns, selectivity optimization, and performance enhancement. This comprehensive review highlights the immense potential of ZIF/GO hybrid materials for multifaceted applications in nanotechnology, providing valuable insights for researchers and paving the way for future advancements in the field.

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来源期刊
FlatChem
FlatChem Multiple-
CiteScore
8.40
自引率
6.50%
发文量
104
审稿时长
26 days
期刊介绍: FlatChem - Chemistry of Flat Materials, a new voice in the community, publishes original and significant, cutting-edge research related to the chemistry of graphene and related 2D & layered materials. The overall aim of the journal is to combine the chemistry and applications of these materials, where the submission of communications, full papers, and concepts should contain chemistry in a materials context, which can be both experimental and/or theoretical. In addition to original research articles, FlatChem also offers reviews, minireviews, highlights and perspectives on the future of this research area with the scientific leaders in fields related to Flat Materials. Topics of interest include, but are not limited to, the following: -Design, synthesis, applications and investigation of graphene, graphene related materials and other 2D & layered materials (for example Silicene, Germanene, Phosphorene, MXenes, Boron nitride, Transition metal dichalcogenides) -Characterization of these materials using all forms of spectroscopy and microscopy techniques -Chemical modification or functionalization and dispersion of these materials, as well as interactions with other materials -Exploring the surface chemistry of these materials for applications in: Sensors or detectors in electrochemical/Lab on a Chip devices, Composite materials, Membranes, Environment technology, Catalysis for energy storage and conversion (for example fuel cells, supercapacitors, batteries, hydrogen storage), Biomedical technology (drug delivery, biosensing, bioimaging)
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