含有活性碳复合材料和相变材料的增强石膏板,具有先进的热能储存和电磁干扰屏蔽性能

Micro Pub Date : 2024-01-24 DOI:10.3390/micro4010005
Christina Gioti, K. Vasilopoulos, M. Baikousi, C. Salmas, Angelos Ntaflos, A. Paipetis, Z. Viskadourakis, R. Ikram, Simeon Agathopoulos, G. Kenanakis, M. Karakassides
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摘要

这项研究介绍了用于先进热能储存(TES)和电磁干扰(EMI)屏蔽应用的新型石膏板复合材料的开发情况。从废咖啡中提取的高比表面积(SBET = 1372 m2/g)活性炭(AC)被用作形状稳定剂,而商用石蜡 RT18HC 被用作有机封装相变材料(PCM)。作为 PCM 的形状稳定剂,AC 显示出卓越的封装效率,约为 120.9 wt%(RT18HC),而形状稳定的 PCM 的熔化焓(ΔHm)为 117.3 J/g。通过将这种 PCM/ 碳纳米复合材料加入石膏墙板等建筑构件中,对其作为热能储存材料的性能进行了检验。使用 X 射线显微层析技术检测了这些先进板材的微观结构、密度和添加剂的分散情况。它们的热调节性能是通过一个自行设计的房间模型和一个类似的自制环境室进行测量的,该环境室能够在加热和冷却过程中创造一个围绕测试房间的均匀温度环境。测量结果表明,与普通石膏板相比,先进的石膏板可将温度波动和房间模型的室内温度降低 2-5%。所研究的石膏板复合样本在 3.5-7.0 GHz 频率范围内显示出高效的电磁屏蔽性能,在填充 PCM 时,电磁干扰值达到约 12.5 dB,符合商业应用的要求。
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Enhanced Gypsum Boards with Activated Carbon Composites and Phase Change Materials for Advanced Thermal Energy Storage and Electromagnetic Interference Shielding Properties
This work presents the development of novel gypsum board composites for advanced thermal energy storage (TES) and electromagnetic interference (EMI) shielding applications. Activated carbon (AC) derived from spent coffee with a high surface area (SBET = 1372 m2/g) was used as a shape stabilizer, while the commercial paraffin, RT18HC, was used as organic encapsulant phase change material (PCM). The AC showed a remarkable encapsulation efficiency as a shape stabilizer for PCM, with ~120.9 wt% (RT18HC), while the melting enthalpy (ΔHm) of the shape-stabilized PCM was 117.3 J/g. The performance of this PCM/carbon nanocomposite as a thermal energy storage material was examined by incorporating it into building components, such as gypsum wallboards. The microstructure of these advanced panels, their density, and their dispersion of additives were examined using X-ray microtomography. Their thermal-regulated performance was measured through a self-designed room model with a similar homemade environmental chamber that was able to create a uniform temperature environment, surrounding the test room during heating and cooling. The measurements showed that the advanced panels reduce temperature fluctuations and the indoor temperature of the room model, in comparison with normal gypsum panels, by a range of 2–5%. The investigated gypsum board composite samples showed efficient electromagnetic shielding performance in a frequency range of 3.5–7.0 GHz, reaching an EMI value of ~12.5 dB, which is adequate and required for commercial applications, when filled with PCMs.
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