描述碳

IF 3.1 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Carbon Trends Pub Date : 2024-01-22 DOI:10.1016/j.cartre.2024.100325
Marc Monthioux
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引用次数: 0

摘要

碳材料因其多样性而成为一种独特的材料,这得益于三种可能的杂化状态(sp、sp2、sp3)、在各种外部压力(热、机械、压力......)作用下从一种相态转换到另一种相态的能力,以及石墨烯(sp2C)对多种缺陷的耐受性。由于缺乏标准化词汇,以及对现有词汇的误用或无知,这使得对石墨烯的描述十分困难。我们需要一种通用语言,以便每个词对每个人都有相同的含义,并使碳科学家尽可能准确地相互理解。本文旨在根据现有的权威出版物,通过提醒一些重要的定义或术语,如同素异形体、多态性、分子形式、晶粒、石墨化、石墨烯、石墨烯层、石墨烯、石墨化、石墨化处理......,来澄清这方面使用的基本术语。此外,由于基于 sp2C 的碳材料表现出最大的可变性,我们提出并论证了一个四项描述方案(即:形态、质地、纳米质地、结构),认为该方案足以(也必须)描述除分子形态之外的任何种类的碳。应用所提出的建议有望使即将出版的有关碳材料的文献更加一致、清晰和易懂。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Describing carbons

Carbon materials are unique materials for their diversity, owing to three possible hybridisation states (sp, sp2, sp3), their ability to switch from one phase to another upon various external stresses (thermal, mechanical, pressure…), and the tolerance of graphene (sp2C) to defects of many kinds. This makes their description difficult, due to the lack of standardised vocabulary and misuses or ignorance of the existing ones. A common language is needed so that every word has the same meaning to everyone and that carbon scientists understand each other as accurately as possible. This paper aims to clarify the basic terminology to be used on this matter, by reminding some important definitions or terms, e.g. allotrope, polymorphism, molecular form, crystallite, graphitic, graphene, graphene layer, graphenic, graphitisation, graphitisation treatment..., based on authoritative publications when available. In addition, as sp2C-based carbon materials exhibit the largest variability, a four-term description scheme (namely: morphology, texture, nanotexture, structure) is proposed and argued, which is believed to be sufficient (and necessary) to describe any kind of carbons, but molecular forms. Applying the recommendations proposed is expected to bring more consistency, clarity, and understandability to the forthcoming literature dealing with carbon materials.

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来源期刊
Carbon Trends
Carbon Trends Materials Science-Materials Science (miscellaneous)
CiteScore
4.60
自引率
0.00%
发文量
88
审稿时长
77 days
期刊最新文献
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