开发作为可持续催化剂的新一代共价有机框架:合成、特性、类型和太阳能生产

IF 31.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials Science and Engineering: R: Reports Pub Date : 2024-02-01 DOI:10.1016/j.mser.2024.100771
Asif Hayat , Saleem Raza , Mohammed A. Amin , Zeeshan Ajmal , Majed M. Alghamdi , Adel A. El-Zahhar , Hamid Ali , Djamel Ghernaout , Yas Al-Hadeethi , Muhammad Sohail , Yasin Orooji
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引用次数: 0

摘要

共价有机框架(COFs)是一种结晶多孔有机聚合物,具有持久的渗透性和稳定的配位框架。与传统的常规聚合物相比,COF 具有功能可持续性,同时又不影响合成的可控性和调整预先设计的物理结构的灵活性,因此是一种令人兴奋的聚合物材料。拓扑设计模式可以将扩展的可渗透多边形控制在特定的结构模式中。共缩合技术有助于利用合成程序生成预配置的基本结构和高度有序的结构。近年来,这两种成分的化学作用取得了重大进展,为 COFs 领域奠定了基础。COFs 在创新有机纳米材料领域的出现,为复杂结构的设计和量身定制的操作增强提供了有效的化学框架,因为它具有化学亚基的可用性以及拓扑结构和链接的多样性。我们的目标是对 COF 研究领域进行全面分析,通过研究 COF 的基本方面,特别是在构型设置和化学合成相互作用方面取得的进展,提供一个历史视角,以展示系统内的各种功能和差异,通过描述基于与光电子、光子、间隙、自旋、原子和粒子的相互关系的结构能力关联,突出推动该领域进步和多种能力潜力的核心研究,以解决关键和具有挑战性的问题。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Developing new-generation covalent organic frameworks as sustainable catalysts: Synthesis, properties, types and solar energy production

Covalent organic frameworks (COFs) are crystallized porous organic polymers with persistent permeability and stable coordinated frameworks. COFs functional sustainability without compromising on controllability in synthesis and flexibility in tuning pre-designed physical structure makes it an exciting polymeric material in comparison to traditional regular ones. The topology design patterns can govern the extended permeable polygon in a particular structured pattern. Co-condensation techniques facilitate the generation of pre-configured basic and highly ordered configurations using synthetic procedures. These two components chemical interactions have made significant advancements in the recent years to establish the basis of the COFs field. COFs emergence in the domain of innovative organic nanomaterials offers an effective chemical framework for complex structured design and tailored operational enhancement because of the availability of chemical subunits and the diverse range of topologies and linkages. We aim to conduct a comprehensive analysis of the COF research field, offering a historical perspective on the fundamental aspects of COFs by examining the progress made, especially, in configuration setup and chemically synthesized interactions, to demonstrate the various functionalities and differences within the system to highlight the core investigations progressing the advancements in field and potential of multiple capabilities by describing the structural capability associations based on interrelationships with photoelectrons, photons, gaps, spins, atoms, and particles, to address the critical and challenging concerns.

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来源期刊
Materials Science and Engineering: R: Reports
Materials Science and Engineering: R: Reports 工程技术-材料科学:综合
CiteScore
60.50
自引率
0.30%
发文量
19
审稿时长
34 days
期刊介绍: Materials Science & Engineering R: Reports is a journal that covers a wide range of topics in the field of materials science and engineering. It publishes both experimental and theoretical research papers, providing background information and critical assessments on various topics. The journal aims to publish high-quality and novel research papers and reviews. The subject areas covered by the journal include Materials Science (General), Electronic Materials, Optical Materials, and Magnetic Materials. In addition to regular issues, the journal also publishes special issues on key themes in the field of materials science, including Energy Materials, Materials for Health, Materials Discovery, Innovation for High Value Manufacturing, and Sustainable Materials development.
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