疏水梯度优化燃料电池气体扩散介质,使其适用于汽车

IF 6.2 3区 综合性期刊 Q1 Multidisciplinary Fundamental Research Pub Date : 2024-09-01 DOI:10.1016/j.fmre.2024.01.007
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引用次数: 0

摘要

在燃料电池汽车(FCV)运行过程中,气体扩散介质(GDM)中的液态水会阻碍反应气体到达反应区,从而导致输出功率波动并缩短 FCV 的使用寿命。本研究优化了微孔层(MPL)和气体扩散层(GDL)的疏水梯度设置,以提高 GDM 的脱水能力。建立了计算流体动力学(CFD)模型进行数值模拟,以分析燃料电池的功率输出和不同疏水性梯度下 GDM 中的含水量。为了验证模拟结果,还进行了不同疏水性梯度的实验,这些疏水性梯度是用相应浓度的聚四氟乙烯(PTFE)溶液专门制备的。结果表明,MPL 和 GDL 的正疏水梯度具有更好的脱水和氧气传输能力。通过与 CFD 模拟相结合的遗传算法,MPL 和 GDL 的接触角进一步优化为 147.9°-138.6°。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Hydrophobicity gradient optimization of fuel cell gas diffusion media for its application in vehicles
During Fuel Cell Vehicle (FCV) operation, the liquid water in gas diffusion media (GDM) prevents the reaction gas from reaching the reaction zone and lead to output power fluctuation and reduce the lifespan of FCV. In the present research, hydrophobicity gradient settings of micro-porous layer (MPL) and gas diffusion layer (GDL) are optimized to improve the water removal ability of GDM. Computational fluid dynamics (CFD) model is constructed for numerical simulations to analyze the fuel cell power output and the water content in the GDM with different hydrophobicity gradients. Experiments with different hydrophobicity gradients, which are specifically prepared with corresponding concentrations of polytetrafluoroethylene (PTFE) solutions, are conducted for validation of simulation results. It is shown that the positive hydrophobicity gradient of MPL and GDL provides a better capacity for water removal and oxygen transport. The contact angles of MPL and GDL are further optimized as 147.9°-138.6° by genetic algorithm integrated with the CFD simulations.
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来源期刊
Fundamental Research
Fundamental Research Multidisciplinary-Multidisciplinary
CiteScore
4.00
自引率
1.60%
发文量
294
审稿时长
79 days
期刊介绍:
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