将镉硒/锌硒量子点作为分布式三元有机光伏电池活性层的助推器。

IF 2.6 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Beilstein Journal of Nanotechnology Pub Date : 2024-02-02 eCollection Date: 2024-01-01 DOI:10.3762/bjnano.15.14
Gabriela Lewińska, Piotr Jeleń, Zofia Kucia, Maciej Sitarz, Łukasz Walczak, Bartłomiej Szafraniak, Jerzy Sanetra, Konstanty W Marszalek
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引用次数: 0

摘要

有机太阳能电池的材料成本低,生产程序简单,因此很有希望得到实际应用。目前面临的挑战是如何选择具有合适特性的材料,以及这些材料在制造设备时的相互关系。本文介绍了在聚合物-富勒烯基质中将镉硒/锌硒纳米点作为掺杂剂应用于有机太阳能电池的研究。聚(3-己基噻吩-2,5-二基)和 6,6-苯基-C71-丁酸甲酯的组合物被用作活性参考层。研究了吸收和发光光谱以及折射率和消光系数的色散关系。用原子力显微镜研究了薄膜的形态。拉曼光谱测定了三元层的化学边界。在 UPS 研究的基础上,确定了潜在装置的能量图。利用阻抗光谱测定了层的电阻率。模拟(通用光伏器件模型)显示,与不含量子点的电池相比,含量子点的电池性能提高了 0.36-1.45%。
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CdSe/ZnS quantum dots as a booster in the active layer of distributed ternary organic photovoltaics.

Organic solar cells are a promising candidate for practical use because of their low material cost and simple production procedures. The challenge is selecting materials with the right properties and how they interrelate in the context of manufacturing the device. This paper presents studies on CdSe/ZnS nanodots as dopants in a polymer-fullerene matrix for application in organic solar cells. An assembly of poly(3-hexylthiophene-2,5-diyl) and 6,6-phenyl-C71-butyric acid methyl ester was used as the active reference layer. Absorption and luminescence spectra as well as the dispersion relations of refractive indices and extinction coefficient were investigated. The morphologies of the thin films were studied with atomic force microscopy. The chemical boundaries of the ternary layers were determined by Raman spectroscopy. Based on UPS studies, the energy diagram of the potential devices was determined. The resistivity of the layers was determined using impedance spectroscopy. Simulations (General-Purpose Photovoltaic Device Model) showed a performance improvement in the cells with quantum dots of 0.36-1.45% compared to those without quantum dots.

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来源期刊
Beilstein Journal of Nanotechnology
Beilstein Journal of Nanotechnology NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
5.70
自引率
3.20%
发文量
109
审稿时长
2 months
期刊介绍: The Beilstein Journal of Nanotechnology is an international, peer-reviewed, Open Access journal. It provides a unique platform for rapid publication without any charges (free for author and reader) – Platinum Open Access. The content is freely accessible 365 days a year to any user worldwide. Articles are available online immediately upon publication and are publicly archived in all major repositories. In addition, it provides a platform for publishing thematic issues (theme-based collections of articles) on topical issues in nanoscience and nanotechnology. The journal is published and completely funded by the Beilstein-Institut, a non-profit foundation located in Frankfurt am Main, Germany. The editor-in-chief is Professor Thomas Schimmel – Karlsruhe Institute of Technology. He is supported by more than 20 associate editors who are responsible for a particular subject area within the scope of the journal.
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