昆虫供电的电化学电容器:蟋蟀生物质的潜力

IF 3.1 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Carbon Trends Pub Date : 2024-02-09 DOI:10.1016/j.cartre.2024.100329
Julien Lemieux , Imran Aslam , Vincent Lemmens , Guy Van den Mooter , Gordana Backović , Samuel Eyley , Wim Thielemans
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引用次数: 0

摘要

昆虫生物质富含甲壳素和壳聚糖,是一种可持续的丰富资源,在推进绿色能源存储解决方案方面大有可为。在本研究中,我们将蟋蟀粉作为电化学电容器中碳电极的候选生物质进行了探索,目的是在碳化过程中创造一种高氮含量的材料。优化后的材料比表面积超过 3300 m2/g,大部分孔隙直径在 0.5-2 nm 范围内。在对称式世伟洛克电池中,这种材料表现出卓越的性能,在 6 M KOH、1 M H2SO4 和 9.2 M NaClO4 电解质中,1 A/g 时的电容量分别为 273.5 F/g、200.2 F/g 和 161.6 F/g。此外,在 1 M H2SO4 和 6 M KOH 中循环 5000 次后,其容量保持率分别为 89.6% 和 87.9%。这种基于蟋蟀的电化学电容器具有强大的循环稳定性,表明它适合长期使用。由此产生的器件具有极高的比电容,有望成为储能应用的候选器件。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Insect-powered electrochemical capacitors: The potential of cricket biomass

Insect biomass, rich in chitin and chitosan, is a sustainable and abundant resource with substantial promise for advancing green energy storage solutions. In this study, we explored cricket flour as a biomass candidate for carbon electrodes in electrochemical capacitors, aiming at creating a material with a high nitrogen content upon carbonization. The optimized material boasted a specific surface area exceeding 3300 m2/g, with most pores falling within the 0.5–2 nm diameter range. In a symmetrical Swagelok-type cell, this material delivered exceptional performance, yielding capacitances of 273.5 F/g, 200.2 F/g, and 161.6 F/g at 1 A/g in 6 M KOH, 1 M H2SO4, and 9.2 M NaClO4 electrolytes, respectively. Furthermore, it showcased a capacity retention of 89.6 % and 87.9 % over 5000 cycles in 1 M H2SO4 and 6 M KOH, respectively. The cricket-based electrochemical capacitor exhibited robust cycling stability, suggesting its suitability for prolonged use. The resulting device demonstrated remarkably high specific capacitance, positioning it as a promising candidate for energy storage applications.

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来源期刊
Carbon Trends
Carbon Trends Materials Science-Materials Science (miscellaneous)
CiteScore
4.60
自引率
0.00%
发文量
88
审稿时长
77 days
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