Julien Lemieux , Imran Aslam , Vincent Lemmens , Guy Van den Mooter , Gordana Backović , Samuel Eyley , Wim Thielemans
{"title":"昆虫供电的电化学电容器:蟋蟀生物质的潜力","authors":"Julien Lemieux , Imran Aslam , Vincent Lemmens , Guy Van den Mooter , Gordana Backović , Samuel Eyley , Wim Thielemans","doi":"10.1016/j.cartre.2024.100329","DOIUrl":null,"url":null,"abstract":"<div><p>Insect biomass, rich in chitin and chitosan, is a sustainable and abundant resource with substantial promise for advancing green energy storage solutions. In this study, we explored cricket flour as a biomass candidate for carbon electrodes in electrochemical capacitors, aiming at creating a material with a high nitrogen content upon carbonization. The optimized material boasted a specific surface area exceeding 3300 m<sup>2</sup>/g, with most pores falling within the 0.5–2 nm diameter range. In a symmetrical Swagelok-type cell, this material delivered exceptional performance, yielding capacitances of 273.5 F/g, 200.2 F/g, and 161.6 F/g at 1 A/g in 6 M KOH, 1 M H<sub>2</sub>SO<sub>4</sub>, and 9.2 M NaClO<sub>4</sub> electrolytes, respectively. Furthermore, it showcased a capacity retention of 89.6 % and 87.9 % over 5000 cycles in 1 M H<sub>2</sub>SO<sub>4</sub> and 6 M KOH, respectively. The cricket-based electrochemical capacitor exhibited robust cycling stability, suggesting its suitability for prolonged use. The resulting device demonstrated remarkably high specific capacitance, positioning it as a promising candidate for energy storage applications.</p></div>","PeriodicalId":52629,"journal":{"name":"Carbon Trends","volume":"14 ","pages":"Article 100329"},"PeriodicalIF":3.1000,"publicationDate":"2024-02-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667056924000105/pdfft?md5=3c5ff6ccf3e479bbf41f1e4c05373503&pid=1-s2.0-S2667056924000105-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Insect-powered electrochemical capacitors: The potential of cricket biomass\",\"authors\":\"Julien Lemieux , Imran Aslam , Vincent Lemmens , Guy Van den Mooter , Gordana Backović , Samuel Eyley , Wim Thielemans\",\"doi\":\"10.1016/j.cartre.2024.100329\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Insect biomass, rich in chitin and chitosan, is a sustainable and abundant resource with substantial promise for advancing green energy storage solutions. In this study, we explored cricket flour as a biomass candidate for carbon electrodes in electrochemical capacitors, aiming at creating a material with a high nitrogen content upon carbonization. The optimized material boasted a specific surface area exceeding 3300 m<sup>2</sup>/g, with most pores falling within the 0.5–2 nm diameter range. In a symmetrical Swagelok-type cell, this material delivered exceptional performance, yielding capacitances of 273.5 F/g, 200.2 F/g, and 161.6 F/g at 1 A/g in 6 M KOH, 1 M H<sub>2</sub>SO<sub>4</sub>, and 9.2 M NaClO<sub>4</sub> electrolytes, respectively. Furthermore, it showcased a capacity retention of 89.6 % and 87.9 % over 5000 cycles in 1 M H<sub>2</sub>SO<sub>4</sub> and 6 M KOH, respectively. The cricket-based electrochemical capacitor exhibited robust cycling stability, suggesting its suitability for prolonged use. The resulting device demonstrated remarkably high specific capacitance, positioning it as a promising candidate for energy storage applications.</p></div>\",\"PeriodicalId\":52629,\"journal\":{\"name\":\"Carbon Trends\",\"volume\":\"14 \",\"pages\":\"Article 100329\"},\"PeriodicalIF\":3.1000,\"publicationDate\":\"2024-02-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2667056924000105/pdfft?md5=3c5ff6ccf3e479bbf41f1e4c05373503&pid=1-s2.0-S2667056924000105-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Carbon Trends\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2667056924000105\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Carbon Trends","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2667056924000105","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
昆虫生物质富含甲壳素和壳聚糖,是一种可持续的丰富资源,在推进绿色能源存储解决方案方面大有可为。在本研究中,我们将蟋蟀粉作为电化学电容器中碳电极的候选生物质进行了探索,目的是在碳化过程中创造一种高氮含量的材料。优化后的材料比表面积超过 3300 m2/g,大部分孔隙直径在 0.5-2 nm 范围内。在对称式世伟洛克电池中,这种材料表现出卓越的性能,在 6 M KOH、1 M H2SO4 和 9.2 M NaClO4 电解质中,1 A/g 时的电容量分别为 273.5 F/g、200.2 F/g 和 161.6 F/g。此外,在 1 M H2SO4 和 6 M KOH 中循环 5000 次后,其容量保持率分别为 89.6% 和 87.9%。这种基于蟋蟀的电化学电容器具有强大的循环稳定性,表明它适合长期使用。由此产生的器件具有极高的比电容,有望成为储能应用的候选器件。
Insect-powered electrochemical capacitors: The potential of cricket biomass
Insect biomass, rich in chitin and chitosan, is a sustainable and abundant resource with substantial promise for advancing green energy storage solutions. In this study, we explored cricket flour as a biomass candidate for carbon electrodes in electrochemical capacitors, aiming at creating a material with a high nitrogen content upon carbonization. The optimized material boasted a specific surface area exceeding 3300 m2/g, with most pores falling within the 0.5–2 nm diameter range. In a symmetrical Swagelok-type cell, this material delivered exceptional performance, yielding capacitances of 273.5 F/g, 200.2 F/g, and 161.6 F/g at 1 A/g in 6 M KOH, 1 M H2SO4, and 9.2 M NaClO4 electrolytes, respectively. Furthermore, it showcased a capacity retention of 89.6 % and 87.9 % over 5000 cycles in 1 M H2SO4 and 6 M KOH, respectively. The cricket-based electrochemical capacitor exhibited robust cycling stability, suggesting its suitability for prolonged use. The resulting device demonstrated remarkably high specific capacitance, positioning it as a promising candidate for energy storage applications.