Hongtao Xia, Yuting Liu, Yang Wang, Zihao Feng, Qi Ren, Jianqi Lv, Yang Li, Yanjun Du, Yun Wang
{"title":"将植酸掺入芦苇秸秆衍生的水炭中以高效、选择性地吸附铀(VI)","authors":"Hongtao Xia, Yuting Liu, Yang Wang, Zihao Feng, Qi Ren, Jianqi Lv, Yang Li, Yanjun Du, Yun Wang","doi":"10.1515/ract-2023-0250","DOIUrl":null,"url":null,"abstract":"An innovative phytic acid modified reed straw-derived hydrochar composite (PA-C-RBC) was prepared by using inexpensive reed straw and non-toxic phytic acid for the removal of uranium(VI) from aqueous environment. Several characterization results showed that PA-C-RBC was rough and porous with a large number of hydroxyl, carboxyl, and phosphate groups. The uranium(VI) adsorption process by PA-C-RBC conformed to pseudo-second-order kinetic and Langmuir models, and the theoretical maximal adsorption capacity could attain 418.78 mg/g at pH 5.0. PA-C-RBC had 72.66 % of selectivity and 6772.99 mL/g of distribution coefficient for U(VI). Due to the strong chelating between the hydroxyl and phosphate groups on PA-C-RBC and U(VI), PA-C-RBC had excellent adsorption selectivity. These finding highlighted a high potential for removing U(VI) from aqueous solutions.","PeriodicalId":21167,"journal":{"name":"Radiochimica Acta","volume":null,"pages":null},"PeriodicalIF":1.4000,"publicationDate":"2024-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Incorporation of phytic acid into reed straw-derived hydrochar for highly efficient and selective adsorption of uranium(VI)\",\"authors\":\"Hongtao Xia, Yuting Liu, Yang Wang, Zihao Feng, Qi Ren, Jianqi Lv, Yang Li, Yanjun Du, Yun Wang\",\"doi\":\"10.1515/ract-2023-0250\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"An innovative phytic acid modified reed straw-derived hydrochar composite (PA-C-RBC) was prepared by using inexpensive reed straw and non-toxic phytic acid for the removal of uranium(VI) from aqueous environment. Several characterization results showed that PA-C-RBC was rough and porous with a large number of hydroxyl, carboxyl, and phosphate groups. The uranium(VI) adsorption process by PA-C-RBC conformed to pseudo-second-order kinetic and Langmuir models, and the theoretical maximal adsorption capacity could attain 418.78 mg/g at pH 5.0. PA-C-RBC had 72.66 % of selectivity and 6772.99 mL/g of distribution coefficient for U(VI). Due to the strong chelating between the hydroxyl and phosphate groups on PA-C-RBC and U(VI), PA-C-RBC had excellent adsorption selectivity. These finding highlighted a high potential for removing U(VI) from aqueous solutions.\",\"PeriodicalId\":21167,\"journal\":{\"name\":\"Radiochimica Acta\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2024-02-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Radiochimica Acta\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1515/ract-2023-0250\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Radiochimica Acta","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1515/ract-2023-0250","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Incorporation of phytic acid into reed straw-derived hydrochar for highly efficient and selective adsorption of uranium(VI)
An innovative phytic acid modified reed straw-derived hydrochar composite (PA-C-RBC) was prepared by using inexpensive reed straw and non-toxic phytic acid for the removal of uranium(VI) from aqueous environment. Several characterization results showed that PA-C-RBC was rough and porous with a large number of hydroxyl, carboxyl, and phosphate groups. The uranium(VI) adsorption process by PA-C-RBC conformed to pseudo-second-order kinetic and Langmuir models, and the theoretical maximal adsorption capacity could attain 418.78 mg/g at pH 5.0. PA-C-RBC had 72.66 % of selectivity and 6772.99 mL/g of distribution coefficient for U(VI). Due to the strong chelating between the hydroxyl and phosphate groups on PA-C-RBC and U(VI), PA-C-RBC had excellent adsorption selectivity. These finding highlighted a high potential for removing U(VI) from aqueous solutions.
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