基于 Ce(OH)4 的纳米晶材料:用于高碱性放射性废液的钌选择性吸附剂

IF 1.4 3区 化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR Radiochimica Acta Pub Date : 2024-02-13 DOI:10.1515/ract-2023-0194
Jayaprakasam Selvakumar, Kumari Anshul, Padala A. Nishad, Bhaskarapillai Anupkumar, Subramanian Srinivasan, Nethapakkam R. Jawahar, Appadurai L. Rufus, Jayantha K. Gayen, Tulasi V. Krishna Mohan
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引用次数: 0

摘要

氢氧化铈(Ce(OH)4 (Ce))已被合成并评估为一种处理碱性放射性液体废物的 Ru 选择性吸附剂。红外光谱、热分析、扫描电子显微镜和能量色散 X 射线光谱研究证实,Ce(NO3)3-6H2O 成功地形成了纳米晶 Ce。使用高纯锗(HPGe)伽马射线光谱仪评估了 Ce 从中级液体废物(ILW)离子交换流出物中选择性去除 106Ru 的情况。计算得出的平均分布系数(k D)为 200 mL/g。通过改变时间、[106Ru]和[Ce],计算了利用 Ce 去除 106Ru 的百分比。106Ru 在 Ce 上的吸附遵循伪二阶和 Freundlich 等温线。计算得出的最大 Q 值为 93,584 Bq/g。对含有 Ru 的 Ce 水泥产品进行了加速沥滤研究,发现其适合运输和处置。此外,还制备了 Ce 聚醚砜(Ce-PES)和 Ce 壳聚糖(CeC)复合材料,并对其在工程规模应用中的 Ru 吸收能力进行了评估。
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Nanocrystalline Ce(OH)4-based materials: ruthenium selective adsorbent for highly alkaline radioactive liquid waste
Cerium hydroxide, Ce(OH)4 (Ce), has been synthesised and assessed as a Ru-selective adsorbent for treating alkaline radioactive liquid waste. Infrared spectroscopy, thermal analysis, scanning electron microscopy, and energy-dispersive X-ray spectroscopy investigations confirmed the successful formation of nanocrystalline Ce from Ce(NO3)3·6H2O. Selective removal of 106Ru from the ion-exchange effluent of intermediate-level liquid waste (ILW) by Ce was assessed using a high-pure germanium (HPGe) gamma-ray spectrometer. The calculated average distribution coefficient (k D) was ∼200 mL/g. The percentage removal of 106Ru using Ce by varying time, [106Ru] and [Ce] was calculated. The adsorption of 106Ru on Ce follows pseudo-second-order and Freundlich isotherms. The calculated Q max was 93,584 Bq/g. Accelerated leaching studies of the Ru-laden Ce cement product were carried out and found suitable for transport and disposal. Further, Ce-Polyether sulphone (Ce-PES) and Ce-Chitosan (CeC) composites were prepared and assessed for their Ru-uptake capacity for engineering scale application.
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来源期刊
Radiochimica Acta
Radiochimica Acta 化学-核科学技术
CiteScore
2.90
自引率
16.70%
发文量
78
审稿时长
6 months
期刊介绍: Radiochimica Acta publishes manuscripts encompassing chemical aspects of nuclear science and technology.
期刊最新文献
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