将硬质合金石灰废料转化为适销对路的 PCC:机械干扰的影响

E. M. Salleh, Rohaya Othman, S. N. M. Sabri, Z. Mahim
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摘要

乙炔市场预计将受到众多行业(尤其是化学合成、氧-乙炔焊接和金属切割)应用增长的推动。由于用途广泛,乙炔在全球市场上保持稳定增长。然而,乙炔的生产会产生越来越多的电石灰废料,根据《马来西亚环境质量法》,电石灰废料被列为表列废料:EQA 1974》(SW427)的规定,因其碱性较高而被列为计划废物。随着废料数量的增加,有必要对其进行重新利用,以避免处理和处置方面的困难。为了解决这一关键的环境问题,我们利用天然蔗糖溶液,通过可行的碳酸化将碳化石灰废料转化为更适销的产品,即沉淀碳酸钙(PCC)。在碳化过程中,对搅拌速率进行了调整(即 300、500、700 和 1000 rpm),以研究其对 PCC 形成的影响。增加机械干扰可使时间从 28 分钟大幅缩短至 9 分钟,并使颗粒细化。生产出纯度超过 98% 的 PCC 表明,硬质合金石灰废料已成功转化为高级 PCC,这不仅有助于保护环境的可持续性,还能为工业带来丰厚的利润回报。
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Transforming Carbide Lime Waste into Marketable PCC: Effect of Mechanical Disturbance
The acetylene market is anticipated to be driven by the growing applications across numerous industries particularly chemical synthesis, oxy-acetylene welding, and metal cutting. Attributable to wide-range uses, acetylene witnesses stable growth in the global market. However, the production of acetylene results in increasing generation of carbide lime waste that is classified as a scheduled waste under Malaysian Environmental Quality Act: EQA 1974 (SW427) due to its high alkalinity. The rising amount of the waste has warranted the need for repurposing its usage to avert handling and disposal difficulties. In overcoming this crucial environmental issue, the carbide lime waste was transformed into a more marketable product so-called precipitated calcium carbonate (PCC) via feasible carbonation, promoted using natural sucrose solution. During the carbonation process, stirring rate was manipulated (i.e 300, 500, 700 and 1000 rpm) in investigating its effects on the PCC formation. Increasing the mechanical disturbance resulted in significant time reduction from 28 minutes to only 9 minutes and particle refinement. The production of PCC with purity above 98% suggested that the carbide lime waste was successfully transformed into high-grade PCC, which not only may help in preserving environmental sustainability yet can also offer profitable return to industry.
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