污水处理厂泵站和沉砂池结构中水泥基材料的老化问题

Nedson T. Kashaija, V. Gável, Krett Gergely, Kovago Akos, Miklós Kürthy, Csaba Szabó, Erika Tóth, Zsuzsanna Szabó-Krausz
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摘要

污水处理厂(WWTP)是污水管理的重要基础设施,其耐久性至关重要。由于水泥基材料具有出色的水密性和强度,因此被用于建造污水处理厂。然而,这些材料的性能会受到侵蚀性环境的影响。有关污水处理厂中水泥基材料劣化的现场实验文献很少。本文研究了污水泵站和污水处理厂沉砂结构中水泥基材料的劣化机理。在这两个地点分别对水泥试样进行了 1 个月、2 个月、3 个月和 7 个月的原位实验。使用立体显微镜和扫描电子显微镜检查了试样的物理和形态变化,并使用 X 射线衍射检查了矿物学/固相变化。结果表明,抽水站的试样形成了彩色的表面产物,经证实是次生矿物(即石膏和埃曲石),而砂阱结构中没有彩色的表面产物。结果表明,受废水蒸汽(在泵站中)影响的胶凝材料比受废水液体(在捕砂结构中)影响的胶凝材料具有更高的劣化效果,这表明废水蒸汽比废水液体对胶凝材料具有更强的侵蚀性。
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Deterioration of Cementitious Materials in Wastewater Treatment Plants’ Pumping Stations and Sand-Trap Structures
Wastewater treatment plants (WWTPs) are critical infrastructures for wastewater management, and their durability is crucial. Due to their excellent water tightness and strength, cementitious materials are used to build WWTPs. However, the performance of these materials is affected by aggressive environments. There are few in situ experiments in the literature regarding the deterioration of cementitious materials in WWTPs. This paper investigates their deterioration mechanisms in a sewage pumping station and a sand-trap structure of a WWTP. In situ experiment was conducted by exposing cement specimens in both locations for 1, 2, 3 and 7 months. The physical and morphological changes of the specimens were examined using stereo microscopy and scanning electron microscopy, whereas the mineralogical/solid phase changes were examined using X-ray diffraction. The results showed that the specimens from the pumping station formed colored surface products, which were confirmed to be secondary minerals (i.e., gypsum and ettringite), whereas there were no colored surface products in the sand-trap structure. The results demonstrated that cementitious materials subjected to wastewater vapors (in a pumping station) had higher deterioration effects than those subjected to wastewater liquid (in a sand-trap structure), suggesting that the wastewater vapors are more aggressive toward cementitious materials than wastewater liquids.
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