O. Odunlami, Oluwamayowa Ogunleye, Ojo S. I. Fayomi, M. Fajobi
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引用次数: 0
摘要
由于非有害抑制剂的重要性,人们开始将药物用作减轻金属材料腐蚀的药剂。本研究采用电位极化、开路电位和失重法揭示了氯苯那敏药物(CD)在盐酸溶液中对低碳钢的抑制反应和吸附机理。在 298 K 的温度下,将 CD 抑制剂配比成 2.5、5、7.5 和 10 毫升,而盐酸的摩尔浓度则按 0.1、0.5、1.0 和 1.5M 的比例变化。结果表明,CD 抑制剂能保护钢材免受腐蚀破坏。当 CD 浓度为 10 毫升时,最佳效率为 85.80%。CD 抑制剂服从 Freundlich 等温线定律,平均回归值为 R2 = 0.9733,R2 值接近于 1。扫描电子显微镜(SEM)和能量色散 X 射线光谱(EDX)结果也证实了 CD 抑制剂在低碳钢样品上的强吸附机制。关键词氯苯那敏药物;绿色抑制剂;开路电位;电位极化;低碳钢
Corrosion Evaluation and Inhibiting Effect of Chlorpheniramine Drug on Mild Steel in HCl Acid
The importance of non harmful inhibitors has informed the application of drugs as an agent to mitigate corrosion of metal materials. This research reveals the inhibitive reaction and adsorption mechanism of Chlorpheniramine drug (CD), on mild steel in an HCl solution using Potentiodynamic polarization, open circuit potential and weight loss method. The CD inhibitor was proportioned into 2.5, 5, 7.5, and 10ml while molarity of HCl was varied in the proportion of 0.1, 0.5, 1.0 and 1.5M at a temperature of 298 K. The reaction showed that as the CD concentration moves to higher concentration, the efficiency of the inhibitor increases, also the higher the concentration of the acid, the higher the corrosion rate. Observation from the result revealed that CD inhibitor protected the steel from corrosion destruction. The optimum efficiency occurred as 85.80% at 10ml CD concentration. CD inhibitor obeyed Freundlich law of isotherm with the average regression value of R2 = 0.9733, as R2 value gets close to unity. Scanning Electron Microscopy (SEM) and Energy-dispersive X-ray spectra (EDX) results also confirm strong adsorption mechanisms of CD inhibitor on the mild steel samples. Keywords: Chlorpheniramine Drug; Green Inhibitor; Open circuit potential; Potentiodynamic Polarization; Mild steel