多腔爆破喷涂法生产的复合涂层的强度和抗裂性结构标准

Volodymyr Korzhyk, Olena M. Berdnikova, Petro Stukhliak, O. Kushnarova, Junjun ZHao, Ihor Skachkov
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引用次数: 0

摘要

现代工业的基本任务是提高产品的可靠性和耐用性。提高产品运行耐久性的有效方法之一是通过高速多室爆破喷涂方法在工作表面涂覆陶瓷和金属陶瓷粉功能涂层。本文的目的是确定金属零件功能性金属陶瓷涂层成型材料中的结构相特征对其强度特性和抗裂性影响的规律性,同时考虑到提供所需的强度和抗裂特性的结构标准。本文开发了一种方法,用于深入细致地分析通过多室引爆喷涂获得的涂层材料的结构特征、相颗粒的形态和分布、其化学计量组成、子结构参数、位错密度。在加速电压高达 200 kV 的 JEM-200CX 仪器(JEOL 公司生产)上使用透射电子显微镜(TEM)对引爆涂层材料进行了研究。研究结果表明了在各种材料(钢、铜、铝、钛)和合金上使用多室引爆喷涂方法的前景。已经获得了一些由铝和锆陶瓷、铬、碳化钨制成的复合涂层。研究表明,在表层不同的加工模式下,下列参数的比例会发生变化:显微硬度、孔隙体积分数、相组成、分散相的分布、晶粒、亚晶粒、位错结构等,而引爆喷涂的模式也会发生相应的变化。
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Strength and Crack Resistance Structural Criteria of Composite Coatings Produced by the Method of Multi-Chamber Detonation Spraying
The essential task of modern industry is to increase the reliability and durability of products. One of the promising ways to increase the products operational durability is the ceramics and cermets powders functional coatings application to the working surfaces by the method of high-speed multi-chamber detonation spraying. The objective of the given paper is to determine the regularities of the influence of structural-phase features in the formed material of functional cermets coatings of metal parts on their strength characteristics and crack resistance, while taking into account structural criteria that will provide the required set of strength and crack resistance properties. The method for deep and detailed analysis of the structure features, morphology and distribution of phase particles, their stoichiometric composition, substructure parameters, dislocation density in the coating material obtained due to multi-chamber detonation spraying has been developed in this paper. The research of detonation coating material was carried out using transmission electron microscopy (TEM) on JEM-200CX instrument (produced by JEOL company) with the accelerating voltage of up to 200 kV. The prospects of using the method of multi-chamber detonation spraying on various materials (steel, copper, aluminum, titanium) and alloys are shown on the basis of the research results. A number of composite coatings made of aluminum and zirconium ceramics; chromium, tungsten carbides have been obtained. It has been defined that changes occur in the ratio of the following parameters: microhardness, pore volume fraction, phase composition, distribution of dispersed phases, grain, subgrain, dislocation structures, etc, under different processing modes in the surface layers and corresponding change in the modes of detonation spraying.
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