通过电化学测试识别混凝土中碳化引起的钢腐蚀

Samanbar Permeh, K. Lau
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摘要

混凝土中碳化引起的钢材腐蚀会导致结构过早退化。健康监测系统中的腐蚀探头可以评估混凝土碳化和钢材腐蚀率。电化学噪声(EN)技术在腐蚀传感方面具有优势。带仪器的混凝土柱安装了一个碳化室,用于加速测试。通过对噪声时间特征、噪声阻抗和频谱分析的统计评估,对 EN 进行了评估。电极的平均噪声电位显示出电负电位和相应的高均方根噪声电流,表明碳化混凝土中的腐蚀活化。噪声阻抗得出的估计腐蚀率与极化电阻和噪声阻抗得出的腐蚀率相当。射击噪声分析表明,孤立的自发噪声事件与局部钢阳极的活化有关。测试结果表明,放置低成本传感器和被动 EN 测量可用于监测混凝土中钢材碳化诱导腐蚀的开始,并提供腐蚀率估计值。
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Identification of carbonation‐induced corrosion of steel in concrete by electrochemical testing
Carbonation‐induced corrosion of steel in concrete can allow for premature degradation of structures. Corrosion probes in health monitoring systems can assess concrete carbonation and steel corrosion rates. The electrochemical noise (EN) technique has advantages for corrosion sensing. Instrumented concrete columns were fitted with a carbonation chamber for accelerated testing. EN was assessed through statistical evaluation of noise time signatures, noise resistance, and spectral analysis. The mean noise potential for the electrodes showed electronegative potential and correspondingly high rms noise current, indicative of corrosion activation in carbonated concrete. The estimated corrosion rates obtained from the noise impedance were comparable to those resolved from the polarization resistance and noise resistance. The shot noise analysis indicated isolated spontaneous noise events associated with the activation of local steel anodes. The outcomes of the testing indicate that the placement of low‐cost sensors and passive EN measurements can be used to monitor the onset of carbonation‐induced corrosion of steel in concrete and provide estimates on corrosion rates.
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