B. Cotrim , T. Bento dos Santos , M.R. Azevedo , P. Cachapuz , D. Carvalho , M. Benoit
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We have constrained the petrological evolution of the anatectic complex (mostly metatexites and diatexites) of the Porto-Viseu Metamorphic Belt in the Central Iberian Zone (CIZ) using petrography, geochemical and isotopic data.</p><p>Major and trace element geochemistry allowed us to conclude that the studied metatexites were formed through water-present melting of muscovite from metapelitic schists, whereas diatexites were mostly formed by dehydration-melting of muscovite and, occasionally, by the dehydration-melting of biotite. Additionally, melting evolution from incipient (metatexites) to pervasive (diatexites and anatectic granitoids) included SiO<sub>2</sub> enrichment and elemental depletion (except for Ca, P, Na and K). The geochemical evolution of these elements during melting progression was essentially controlled by fractionation/melting of plagioclase, K-feldspar, mica and apatite, whereas REE abundance was constrained by accessory minerals, such as monazite, apatite and zircon. In both cases, the geochemical control was variable and dependent on the fate of these mineral phases during the progression of melting, as well as the variable degree of melt loss or gain, with diatexites and granites being the result of substantial melt gain.</p><p>The <sup>87</sup>Sr/<sup>86</sup>Sr<sub>320</sub> values have a large dispersion (0.708–0.766), which is common for rocks that experienced these metamorphic conditions, whereas the εNd<sub>320</sub> values are less variable, roughly from −3 to −9 (diatexites: −8.24 to −2.96; metatexites: −8.79 to −5.15; staurolite-bearing schists: −7.57 to −5.19; granite: −8.21), being both isotopes independent of lithological type or degree of melting. Therefore, we interpret their Sr isotopic variation as mostly related to secondary alteration processes, whereas Nd isotopes, which are usually more immobile, should correlate to the initial protolith. 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引用次数: 0
摘要
伟晶岩的形成取决于几个相互关联的因素,如P-T条件、原岩成分和挥发物的丰度,这通常会阻碍对无性进展及其与造山演化关系的全面了解。我们利用岩石学、地球化学和同位素数据,对伊比利亚中部地区(CIZ)波尔图-维塞乌变质岩带的安山岩复合体(主要是偏闪长岩和二长岩)的岩石学演化进行了约束。通过主要元素和痕量元素地球化学研究,我们得出结论:所研究的偏闪长岩是由偏闪长岩片岩中的黝帘石遇水熔融形成的,而二长岩则主要是由黝帘石脱水熔融形成的,偶尔也有由生物岩脱水熔融形成的。此外,熔融演化从初生(偏闪长岩)到普遍(二闪长岩和安山花岗岩)包括二氧化硅富集和元素贫化(钙、钾、钠和钾除外)。这些元素在熔融过程中的地球化学演变基本上受斜长石、钾长石、云母和磷灰石的分馏/熔融控制,而稀土元素的丰度则受附属矿物(如独居石、磷灰石和锆石)的制约。在这两种情况下,地球化学控制是多变的,取决于这些矿物相在熔融过程中的命运,以及不同程度的熔体损耗或增益,二长岩和花岗岩是大量熔体增益的结果。87Sr/86Sr320值的离散性较大(0.708-0.766),这在经历过这些变质条件的岩石中很常见,而εNd320值的离散性较小,大致在-3到-9之间(二长岩:-8.24到-2:-8.24至-2.96;偏闪长岩:8.79至-5.15;含辉石片岩:-7.57至-5.15):-7.57至-5.19;花岗岩:-8.21),这两种同位素与岩性类型或熔融程度无关。因此,我们认为它们的 Sr 同位素变化主要与次生蚀变过程有关,而 Nd 同位素通常较为固定,应与最初的原岩有关。事实上,它们的同位素结果与其他没有经历过如此高变质条件和熔融过程的 CIZ 变质岩(杜罗-贝拉斯超群)的值基本一致,很可能来自这些岩石,即杜罗群。
Formation and evolution of metapelitic-derived melts within anatectic complexes: Geochemical constraints and inferences on the protoliths and geodynamics of the Porto-Viseu Metamorphic Belt, Central Iberian Zone (central-north Portugal)
Migmatite formation is dependent of several and inter-related factors, such as P-T conditions, protolith composition and the abundance of volatiles, which usually hinders the full understanding of anatectic progression and how it relates to orogenic evolution. We have constrained the petrological evolution of the anatectic complex (mostly metatexites and diatexites) of the Porto-Viseu Metamorphic Belt in the Central Iberian Zone (CIZ) using petrography, geochemical and isotopic data.
Major and trace element geochemistry allowed us to conclude that the studied metatexites were formed through water-present melting of muscovite from metapelitic schists, whereas diatexites were mostly formed by dehydration-melting of muscovite and, occasionally, by the dehydration-melting of biotite. Additionally, melting evolution from incipient (metatexites) to pervasive (diatexites and anatectic granitoids) included SiO2 enrichment and elemental depletion (except for Ca, P, Na and K). The geochemical evolution of these elements during melting progression was essentially controlled by fractionation/melting of plagioclase, K-feldspar, mica and apatite, whereas REE abundance was constrained by accessory minerals, such as monazite, apatite and zircon. In both cases, the geochemical control was variable and dependent on the fate of these mineral phases during the progression of melting, as well as the variable degree of melt loss or gain, with diatexites and granites being the result of substantial melt gain.
The 87Sr/86Sr320 values have a large dispersion (0.708–0.766), which is common for rocks that experienced these metamorphic conditions, whereas the εNd320 values are less variable, roughly from −3 to −9 (diatexites: −8.24 to −2.96; metatexites: −8.79 to −5.15; staurolite-bearing schists: −7.57 to −5.19; granite: −8.21), being both isotopes independent of lithological type or degree of melting. Therefore, we interpret their Sr isotopic variation as mostly related to secondary alteration processes, whereas Nd isotopes, which are usually more immobile, should correlate to the initial protolith. In fact, their isotopic results are broadly consistent to the values of other CIZ metasediments that did not experience such high metamorphic conditions and melting (Douro-Beiras Supergroup), being most likely derived from these rocks, namely the Douro Group.
期刊介绍:
GEOCHEMISTRY was founded as Chemie der Erde 1914 in Jena, and, hence, is one of the oldest journals for geochemistry-related topics.
GEOCHEMISTRY (formerly Chemie der Erde / Geochemistry) publishes original research papers, short communications, reviews of selected topics, and high-class invited review articles addressed at broad geosciences audience. Publications dealing with interdisciplinary questions are particularly welcome. Young scientists are especially encouraged to submit their work. Contributions will be published exclusively in English. The journal, through very personalized consultation and its worldwide distribution, offers entry into the world of international scientific communication, and promotes interdisciplinary discussion on chemical problems in a broad spectrum of geosciences.
The following topics are covered by the expertise of the members of the editorial board (see below):
-cosmochemistry, meteoritics-
igneous, metamorphic, and sedimentary petrology-
volcanology-
low & high temperature geochemistry-
experimental - theoretical - field related studies-
mineralogy - crystallography-
environmental geosciences-
archaeometry