基于聚醚-b-酰胺共聚物的永久性抗静电添加剂的制备及其对聚酰胺 6 的改性效果

IF 2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pure and Applied Chemistry Pub Date : 2024-02-23 DOI:10.1515/pac-2023-1132
Lihui Yuan, Ping Zhu, Yu Wang, Xia Dong, Dujin Wang
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引用次数: 0

摘要

传统聚合物通常用于各种电子设备的包装,但由于其固有的电绝缘特性,这些材料无法消散静电荷。为了解决这个问题,我们通过熔融缩聚法合成了由均匀的刚性草酰胺和柔性聚乙二醇(PEG)组成的新型聚(醚-b-酰胺)(PEBA)分段共聚物。系统研究了 PEG 分子量和两个草酰胺单元之间的间隔长度对缩合结构、机械性能和抗静电性能的影响。傅立叶变换红外光谱(FTIR)显示,草酰胺硬段具有很强的氢键和高度有序性,即使在较低的有序度下,其有序度也在 71% 到 85% 之间。力学行为结果表明,分段共聚物具有明显的屈服点,弹性模量在 20 到 30 兆帕之间,断裂应变超过 2000%。同时,这种共聚物具有较低的表面电阻率,低至 107 Ω,明显低于商用抗静电添加剂。此外,还研究了 PEBA 对聚酰胺 6(PA6)的抗静电效果,结果表明,当含量达到 30 wt% 时,合金的表面电阻率从 1013 Ω 下降到 1011 Ω,并且在 40 天后保持稳定,即使经过水洗处理也是如此。总之,这些研究结果表明,新合成的 PEBA 共聚物具有出色的长期抗静电性能,为开发聚醚基多嵌段共聚物抗静电剂提供了宝贵的启示。
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The preparation of permanent antistatic additive based on poly(ether-b-amide) copolymers and its modification effect on polyamide 6
Conventional polymers have typically been used in the packaging of various electronic devices; however, due to the inherent electrically insulating properties these materials fail to dissipate static charges. To address this issue, novel poly(ether-b-amide) (PEBA) segmented copolymers consisting of uniform rigid oxalamide and flexible polyethylene glycol (PEG) were synthesized via melt polycondensation. The influence of PEG molecular weight and the spacer length separating two oxalamide units on the condensed structure, mechanical performance, and antistatic properties was systematically investigated. Fourier-transform infrared (FTIR) demonstrated strongly hydrogen bonded and highly ordered oxalamide hard segments with the degree of ordering between 71 and 85 % even at low levels. Mechanical behavior results showed that segmented copolymers have an obvious yield point, an elastic modulus between 20 and 30 MPa, and strain at break exceeding 2000 %. Meanwhile, such copolymers possessed low surface resistivity, as low as 107 Ω, which is significantly less than that of commercial antistatic additives. The antistatic effect of PEBA on polyamide 6 (PA6) was also investigated, revealing that when the content reached 30 wt%, the surface resistivity of the alloys decreased from 1013 Ω to 1011 Ω and remained stable after 40 days, even after water washing treatment. Overall, these findings illustrate that the newly synthesized PEBA copolymers demonstrate outstanding long-term antistatic properties and provide valuable insights for the development of polyether-based multiblock copolymer antistatic agents.
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来源期刊
Pure and Applied Chemistry
Pure and Applied Chemistry 化学-化学综合
CiteScore
4.00
自引率
0.00%
发文量
60
审稿时长
3-8 weeks
期刊介绍: Pure and Applied Chemistry is the official monthly Journal of IUPAC, with responsibility for publishing works arising from those international scientific events and projects that are sponsored and undertaken by the Union. The policy is to publish highly topical and credible works at the forefront of all aspects of pure and applied chemistry, and the attendant goal is to promote widespread acceptance of the Journal as an authoritative and indispensable holding in academic and institutional libraries.
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