脉冲激光烧蚀聚合物基磁性纳米复合材料用于溢油修复

Tamás Gera , Bence Kondász , Tomi Smausz , Judit Kopniczky , Szabolcs Hodovány , Tibor Ajtai , Piroska Szabó-Révész , Rita Ambrus , Ildikó Csóka , Béla Hopp
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引用次数: 0

摘要

溢油是一种严重的环境威胁,尤其是对海洋生态系统的威胁,因此有必要开发高效、环保的修复技术。本研究探讨了脉冲激光烧蚀(PLA)在制造聚合物磁性纳米复合材料中的应用,重点是聚乙烯吡咯烷酮、壳聚糖和甲基纤维素。这些聚合物因能吸附各种油类中的污染物而闻名,它们与磁铁矿纳米粒子(NPs)以压缩片剂的形式结合在一起。聚乳酸工艺促进了纳米复合材料的生成,随后利用外部磁场对其进行收集。通过傅立叶变换红外光谱(FTIR)和拉曼光谱分析了这些复合材料的化学成分,同时使用徕卡图像处理和分析系统测定了颗粒尺寸。研究表明,聚乳酸是制备磁性纳米复合材料的一种绿色、单步且有效的技术,其产生的颗粒主要在 400 nm-4 µm 大小范围内。此外,这些复合材料在油/水分离中的应用表明,在施加磁场约 1 秒后就开始分离。这些发现强调了聚乳酸在制作磁性纳米复合材料方面的潜力,可用于快速和环境可持续的石油泄漏修复。
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Pulsed laser ablation of polymer-based magnetic nanocomposites for oil spill remediation

Oil spills represent a critical environmental threat, particularly to marine ecosystems, necessitating the development of efficient and eco-friendly remediation technologies. This study explores the application of pulsed laser ablation (PLA) in fabricating polymer-based magnetic nanocomposites, with a focus on polyvinylpyrrolidone, chitosan, and methyl cellulose. These polymers, renowned for their proficiency in adsorbing pollutants from various oils, were combined with magnetite nanoparticles (NPs) in a compressed tablet form. The PLA process facilitated the generation of nanocomposites, which were subsequently collected using an external magnetic field. The chemical composition of these composites was analyzed through Fourier-transform infrared (FTIR) and Raman spectroscopy, while particle sizes were determined using the Leica Image Processing and Analysis System. The study revealed that PLA is a green, single-step, and effective technique for preparing magnetic nanocomposites, producing particles predominantly in the 400 nm–4 µm size range. Furthermore, the application of these composites in oil/water separation demonstrated with separation commencing approximately 1 s after the application of a magnetic field. These findings underscore the potential of PLA in crafting magnetic nanocomposites for the rapid and environmentally sustainable remediation of oil spills.

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