{"title":"从机理上洞察受挫路易斯配对的反应性：液态核磁共振研究。","authors":"Xinhui Kou","doi":"10.1080/10408347.2024.2324299","DOIUrl":null,"url":null,"abstract":"<p><p>Frustrated Lewis pairs (FLPs) have been widely investigated as promising catalysts due to their metal-free feature and ability to activate small molecules. Over the last few years, the structure, dynamics and interactions between the Lewis centers and their effects on the reactivity with different substrates have been studied. Nuclear magnetic resonance (NMR) is a powerful tool in studying the reaction intermediates, kinetics and mechanism of frustrated Lewis pairs (FLPs). Various NMR experiments have been applied to precisely determine the association or cooperativity of FLPs and one or two-dimensional spectra were obtained. Herein, insights coming from NMR spectroscopy for FLPs are presented, the structure and reactivity of FLPs in solution are described, and their effects on the kinetics and mechanism of different substrates are also illustrated in this review.</p>","PeriodicalId":10744,"journal":{"name":"Critical reviews in analytical chemistry","volume":null,"pages":null},"PeriodicalIF":4.2000,"publicationDate":"2024-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Mechanistic Insight Into the Reactivity of Frustrated Lewis Pairs: Liquid-State NMR Studies.\",\"authors\":\"Xinhui Kou\",\"doi\":\"10.1080/10408347.2024.2324299\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Frustrated Lewis pairs (FLPs) have been widely investigated as promising catalysts due to their metal-free feature and ability to activate small molecules. Over the last few years, the structure, dynamics and interactions between the Lewis centers and their effects on the reactivity with different substrates have been studied. Nuclear magnetic resonance (NMR) is a powerful tool in studying the reaction intermediates, kinetics and mechanism of frustrated Lewis pairs (FLPs). Various NMR experiments have been applied to precisely determine the association or cooperativity of FLPs and one or two-dimensional spectra were obtained. Herein, insights coming from NMR spectroscopy for FLPs are presented, the structure and reactivity of FLPs in solution are described, and their effects on the kinetics and mechanism of different substrates are also illustrated in this review.</p>\",\"PeriodicalId\":10744,\"journal\":{\"name\":\"Critical reviews in analytical chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2024-03-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Critical reviews in analytical chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1080/10408347.2024.2324299\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Critical reviews in analytical chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1080/10408347.2024.2324299","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Mechanistic Insight Into the Reactivity of Frustrated Lewis Pairs: Liquid-State NMR Studies.
Frustrated Lewis pairs (FLPs) have been widely investigated as promising catalysts due to their metal-free feature and ability to activate small molecules. Over the last few years, the structure, dynamics and interactions between the Lewis centers and their effects on the reactivity with different substrates have been studied. Nuclear magnetic resonance (NMR) is a powerful tool in studying the reaction intermediates, kinetics and mechanism of frustrated Lewis pairs (FLPs). Various NMR experiments have been applied to precisely determine the association or cooperativity of FLPs and one or two-dimensional spectra were obtained. Herein, insights coming from NMR spectroscopy for FLPs are presented, the structure and reactivity of FLPs in solution are described, and their effects on the kinetics and mechanism of different substrates are also illustrated in this review.
期刊介绍：
Critical Reviews in Analytical Chemistry continues to be a dependable resource for both the expert and the student by providing in-depth, scholarly, insightful reviews of important topics within the discipline of analytical chemistry and related measurement sciences. The journal exclusively publishes review articles that illuminate the underlying science, that evaluate the field''s status by putting recent developments into proper perspective and context, and that speculate on possible future developments. A limited number of articles are of a "tutorial" format written by experts for scientists seeking introduction or clarification in a new area.
This journal serves as a forum for linking various underlying components in broad and interdisciplinary means, while maintaining balance between applied and fundamental research. Topics we are interested in receiving reviews on are the following:
· chemical analysis;
· instrumentation;
· chemometrics;
· analytical biochemistry;
· medicinal analysis;
· forensics;
· environmental sciences;
· applied physics;
· and material science.
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