{"title":"双[S-辛基 3-(2-甲基亚丙基)二硫代卡巴唑-κ2 N 3 S]镍(II)","authors":"Sultana Shakila Khan , Md. Belayet Hossain Howlader , Md. Chanmiya Sheikh , Ryuta Miyatake , Ennio Zangrando , M. Weil (Editor)","doi":"10.1107/S241431462400186X","DOIUrl":null,"url":null,"abstract":"<div><p>The bis-chelated mononuclear nickel(II) complex shows inversion symmetry, with the dithiocarbazato ligand in the usual <em>trans</em> configuration and the central metal cation in a square-planar coordination environment.</p></div><div><p>The central Ni<sup>II</sup> atom in the title complex, [Ni(C<sub>13</sub>H<sub>25</sub>N<sub>2</sub>S<sub>2</sub>)<sub>2</sub>], is located on an inversion center and adopts a roughly square-planar coordination environment defined by two chelating <em>N</em>,<em>S</em> donor sets of two symmetry-related ligands in a <em>trans</em> configuration. The Ni—N and Ni—S bond lenghts are 1.9193 (14) and 2.1788 (5) Å, respectively, with a chelating N—Ni—S bond angle of 86.05 (4)°. These data are compared with those measured for similar dithiocarbazato ligands that bear <em>n</em>-octyl or <em>n</em>-hexyl alkyl chains. Slight differences are observed with respect to the phenylethylidene derivative where the ligands are bound <em>cis</em> relative to one another. <span><figure><span><img><ol><li><span>Download : <span>Download high-res image (207KB)</span></span></li><li><span>Download : <span>Download full-size image</span></span></li></ol></span></figure></span> </p></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Bis[S-octyl 3-(2-methylpropylidene)dithiocarbazato-κ2 N 3,S]nickel(II)\",\"authors\":\"Sultana Shakila Khan , Md. Belayet Hossain Howlader , Md. Chanmiya Sheikh , Ryuta Miyatake , Ennio Zangrando , M. Weil (Editor)\",\"doi\":\"10.1107/S241431462400186X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The bis-chelated mononuclear nickel(II) complex shows inversion symmetry, with the dithiocarbazato ligand in the usual <em>trans</em> configuration and the central metal cation in a square-planar coordination environment.</p></div><div><p>The central Ni<sup>II</sup> atom in the title complex, [Ni(C<sub>13</sub>H<sub>25</sub>N<sub>2</sub>S<sub>2</sub>)<sub>2</sub>], is located on an inversion center and adopts a roughly square-planar coordination environment defined by two chelating <em>N</em>,<em>S</em> donor sets of two symmetry-related ligands in a <em>trans</em> configuration. The Ni—N and Ni—S bond lenghts are 1.9193 (14) and 2.1788 (5) Å, respectively, with a chelating N—Ni—S bond angle of 86.05 (4)°. These data are compared with those measured for similar dithiocarbazato ligands that bear <em>n</em>-octyl or <em>n</em>-hexyl alkyl chains. Slight differences are observed with respect to the phenylethylidene derivative where the ligands are bound <em>cis</em> relative to one another. <span><figure><span><img><ol><li><span>Download : <span>Download high-res image (207KB)</span></span></li><li><span>Download : <span>Download full-size image</span></span></li></ol></span></figure></span> </p></div>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2414314624000117\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624000117","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Bis[S-octyl 3-(2-methylpropylidene)dithiocarbazato-κ2 N 3,S]nickel(II)
The bis-chelated mononuclear nickel(II) complex shows inversion symmetry, with the dithiocarbazato ligand in the usual trans configuration and the central metal cation in a square-planar coordination environment.
The central NiII atom in the title complex, [Ni(C13H25N2S2)2], is located on an inversion center and adopts a roughly square-planar coordination environment defined by two chelating N,S donor sets of two symmetry-related ligands in a trans configuration. The Ni—N and Ni—S bond lenghts are 1.9193 (14) and 2.1788 (5) Å, respectively, with a chelating N—Ni—S bond angle of 86.05 (4)°. These data are compared with those measured for similar dithiocarbazato ligands that bear n-octyl or n-hexyl alkyl chains. Slight differences are observed with respect to the phenylethylidene derivative where the ligands are bound cis relative to one another.
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