阿托品(2-苯基喹啉-4-羧酸)的新型衍生物

E. Dikusar, E. A. Akishina, S. Stepin, L. N. Filippovich, N. V. Bogdanova, S. N. Shahab, V. Potkin
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引用次数: 0

摘要

在二氯甲烷中,在三乙胺的存在下,用阿托品酰基盐酸盐对取代的羟基苯甲醛进行酰化,得到的酯与胺类(4-氨基偶氮苯、4-氨基安替比林)在甲醇中缩合时,能够形成 (E)- 氮甲基。此外,还获得了阿托芬烷与姜黄素天然片段的酯。研究发现,基于(E)-偶氮甲烷与偶氮苯片段的薄膜具有很强的偏振能力。
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Novel derivatives of atophan (2-phenylquinoline-4-carboxic acid)
Acylation of substituted hydroxybenzaldehydes with hydrochloride of atophane acylchloride in dichloromethane in the presence of triethylamine gave esters, capable of forming (E)-azomethines when condensed with amines (4-aminoazobenzene, 4-aminoantipyrine) in methanol. In addition, an ester of atophane with a natural fragment of curcumin was obtained. Films based on (E)-azomethine with an azobenzene fragment were found to have a high polarizing ability.
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CiteScore
0.30
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0.00%
发文量
38
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