通过金(I)催化的 N-二茂铁基丙炔酰胺的加氢反应对平面手性二茂铁进行对映选择性合成

Green Synthesis and Catalysis Pub Date : 2024-03-08 DOI:10.1016/j.gresc.2024.02.007

Qian Zhou, Lulin Qiao, An-An Zhang, Lu Li, Tuan-Jie Meng, Baomin Fan, Yuan-Yuan Gao, Lantao Liu

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引用次数: 0

摘要

在此，我们报告了一种通过金（I）催化的氢化作用合成平面手性二茂铁的二茂铁丙酰胺分子内环化方法。通过该方法，我们获得了多种平面手性二茂铁吡啶-2(1)-酮，产量高，对映选择性极佳（高达 96%）。

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Enantioselective synthesis of planar chiral ferrocenes via gold(I)-catalyzed hydroarylation of N-ferrocenyl propiolamides

Herein, we report an intramolecular cyclization of -ferrocenyl propiolamides for the synthesis of planar chiral ferrocenes enabled by gold(I)-catalyzed hydroarylation. By using this protocol, a variety of planar chiral ferrocenopyridin-2(1)-ones were obtained in good yields and excellent enantioselectivities (up to 96% ).

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来源期刊

Green Synthesis and Catalysis

CiteScore

14.40

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0.00%

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