竹茎衍生生物炭用于生物吸附受污染废水中的镉(II)离子

Harsh Sable , Vaishali Kumar , Richa Mishra , Vandana Singh , Arpita Roy , Ashutosh Kumar Rai , Nishant Ranjan , Sarvesh Rustagi , Soumya Pandit
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摘要

未经预处理,地表水和环境中的镉含量超过最大允许量就会造成危害。将研究竹茎生物质对重金属污染废水中 Cd2+ 的吸附修复能力,以防止再次发生。实验控制了生物吸附剂的用量、接触长度、pH 值、温度和初始镉浓度,以获得最佳修复效果。Cd2+ 在 pH 值为 5、接触时间为 90 分钟、温度为 298 K 的条件下去除效果最佳。在 298 K 的条件下,90 分钟内吸附了 4.13 mg/g Cd2+,吸附量为 4.17 mg/g。在 qe 为 2.01 毫克/克时,金属离子浓度达到 80.98%,而在 0.05 兆盐酸时,解吸率为 91.3%。动力学研究表明,它遵循 Lagergren 准二阶反应、Langmuir 和 Freundlich 模型。在所有镉浓度下,竹茎生物质的表现都较好,重金属去除率随浓度增加而增加。结果表明,竹茎生物质能有效去除废水中的重金属。扫描电镜显示,生物炭具有纵向孔隙和粗糙的表面。由于生物炭的 XRD 峰尖锐而强烈,因此其氯化钾浓度很高。这些发现表明,竹茎生物质可有效去除废水中的重金属。
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Bamboo stem derived biochar for biosorption of Cadmium (II) ions from contaminated wastewater

Cadmium in surface waters and the environment beyond the maximum allowed quantities without pre-treatment is hazardous. Bamboo stem biomass adsorption capability for Cd2+ remediation from heavy metal-polluted wastewater will be examined to prevent recurrence. The experiment controlled biosorbent dosage, contact length, pH, temperature, and beginning Cadmium concentration for the optimum remediation. Cd2+ was best removed at pH 5 with contact time was 90 min at 298 K. Adsorption observed was 4.17 mg/g at 298 K with 4.13 mg/g Cd2+ sorbed in 90 min. Metal ion concentration reached upto 80.98 % with qe 2.01 mg/g while the desorption 91.3 % at 0.05 M of HCl. The kinetic study showed that it follows Lagergren psuedo-second order reaction, Langmuir, and Freundlich models. The bamboo stem biomass performed better at all cadmium concentrations, with heavy metal removal increasing with concentration. According to the results, bamboo stem biomass is effective in heavy metal removal from wastewater. SEM shows biochar has longitudinal pores and a rough surface. Biochar has significant KCl concentration due to its sharp, strong XRD peaks. These findings suggest that bamboo stem biomass is effective in removing heavy metals from wastewater.

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来源期刊
Environmental Nanotechnology, Monitoring and Management
Environmental Nanotechnology, Monitoring and Management Environmental Science-Water Science and Technology
CiteScore
13.00
自引率
0.00%
发文量
132
审稿时长
48 days
期刊介绍: Environmental Nanotechnology, Monitoring and Management is a journal devoted to the publication of peer reviewed original research on environmental nanotechnologies, monitoring studies and management for water, soil , waste and human health samples. Critical review articles, short communications and scientific policy briefs are also welcome. The journal will include all environmental matrices except air. Nanomaterials were suggested as efficient cost-effective and environmental friendly alternative to existing treatment materials, from the standpoints of both resource conservation and environmental remediation. The journal aims to receive papers in the field of nanotechnology covering; Developments of new nanosorbents for: •Groundwater, drinking water and wastewater treatment •Remediation of contaminated sites •Assessment of novel nanotechnologies including sustainability and life cycle implications Monitoring and Management papers should cover the fields of: •Novel analytical methods applied to environmental and health samples •Fate and transport of pollutants in the environment •Case studies covering environmental monitoring and public health •Water and soil prevention and legislation •Industrial and hazardous waste- legislation, characterisation, management practices, minimization, treatment and disposal •Environmental management and remediation
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