利用聚对苯二甲酸乙二醇酯瓶废料作为合成不饱和聚酯树脂的可行前体,制造黄麻纤维增强复合材料

Devarun Nath, Debasish Das, Santanu Chattopadhyay, Sudipta Sekhar Mahish, Mallika Datta
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摘要

本研究利用乙二醇化聚对苯二甲酸乙二酯(PET)瓶废料作为合成不饱和聚酯树脂(rUPR)的前体。然后利用这种树脂制造复合材料,并采用片状模塑复合技术用黄麻纤维进行增强。通过结合使用差示扫描量热法(DSC)和傅立叶变换红外光谱法(FTIR)分析,阐明了 rUPR 中苯乙烯的有限交联。在傅立叶变换红外光谱(FTIR)中,1152 kJ 的放热反应能量升高,1620 cm-1 处的峰值清晰可辨,为这一现象提供了大量证据。此外,X 射线衍射(XRD)分析表明,回收的不饱和聚酯树脂(rUPR)具有更高的无定形性。将 rUPR 用作基体材料在提高黄麻纤维增强复合材料的拉伸和弯曲性能方面具有显著效果。因此,本研究的目的是利用回收的聚对苯二甲酸乙二酯(rUPR)废料开发一种热固性树脂,以鉴定其是否适合制造以黄麻纤维为增强材料的复合材料。
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Using polyethylene terephthalate bottle waste as a viable precursor for the synthesis of unsaturated polyester resin in fabrication of jute fibre reinforced composites
The present research effort employs glycolysed polyethylene terephthalate (PET) bottle waste as a precursor for the synthesis of unsaturated polyester resin (rUPR). This resin is then used for manufacturing composites that are reinforced with jute fibres using the sheet moulding compound technique. The limited crosslinking of styrene in the rUPR was elucidated using a combination of differential scanning calorimetry (DSC) and Fourier transform infrared spectroscopy (FTIR) analysis. The elevated exothermic reaction energy of 1152 kJ and the clearly identifiable peak observed at 1620 cm−1 in the Fourier Transform Infrared (FTIR) spectrum provided substantial evidence for this phenomenon. Additionally, the X-ray diffraction (XRD) analysis indicated that the recycled unsaturated polyester resin (rUPR) demonstrated a higher level of amorphous nature This observation can be attributed to reduced viscosity and enhanced ductility of rUPR. The utilisation of the rUPR as a matrix material has shown significant effectiveness in enhancing the tensile and flexural properties of composites reinforced with jute fibres. Thereby, the objective of this research is to develop a thermoset resin using recycled polyethylene terephthalate (rUPR) waste material for identification its suitability in manufacturing composites with jute fibres as reinforcement.
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