通过二氧化碳和硝酸盐的电化学共还原生产尿素的前景

IF 7.9 2区 化学 Q1 CHEMISTRY, PHYSICAL Current Opinion in Electrochemistry Pub Date : 2024-03-13 DOI:10.1016/j.coelec.2024.101479
Qinglan Zhao , Yan Zhang , Dapeng Cao , Minhua Shao
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引用次数: 0

摘要

一氧化碳和硝酸盐的电化学共还原为尿素生产提供了一种前景广阔的替代方法。然而,目前尿素的电化学合成面临着选择性低和生产率低的挑战。开发高效电催化剂是提高尿素电合成性能的关键。本微型综述主要侧重于催化剂的合理设计,首先从机理方面进行概述。此外,还讨论了尿素电化学合成电解槽的进展,旨在阐明未来实现达到工业相关水平的高速生产的指导原则。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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The prospects of urea manufacturing via electrochemical co-reduction of CO2 and nitrates

Electrochemical co-reduction of CO2 and nitrates presents a promising alternative for urea production. However, the current electrochemical synthesis of urea faces challenges related to low selectivity and production rates. The development of high-efficiency electrocatalysts is the key to performance improvement of urea electrosynthesis. This minireview primarily focuses on the rational design of catalysts, starting with a mechanistic overview. In addition, the advancement of electrolyzers for urea electrochemical synthesis is also discussed aiming to articulate guiding principles of achieving high-rate production reaching industrial relevant level in the future.

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来源期刊
Current Opinion in Electrochemistry
Current Opinion in Electrochemistry Chemistry-Analytical Chemistry
CiteScore
14.00
自引率
5.90%
发文量
272
审稿时长
73 days
期刊介绍: The development of the Current Opinion journals stemmed from the acknowledgment of the growing challenge for specialists to stay abreast of the expanding volume of information within their field. In Current Opinion in Electrochemistry, they help the reader by providing in a systematic manner: 1.The views of experts on current advances in electrochemistry in a clear and readable form. 2.Evaluations of the most interesting papers, annotated by experts, from the great wealth of original publications. In the realm of electrochemistry, the subject is divided into 12 themed sections, with each section undergoing an annual review cycle: • Bioelectrochemistry • Electrocatalysis • Electrochemical Materials and Engineering • Energy Storage: Batteries and Supercapacitors • Energy Transformation • Environmental Electrochemistry • Fundamental & Theoretical Electrochemistry • Innovative Methods in Electrochemistry • Organic & Molecular Electrochemistry • Physical & Nano-Electrochemistry • Sensors & Bio-sensors •
期刊最新文献
Determination of the reaction orders for electrode reactions Electrochemical systems for renewable energy conversion and storage: Focus on flow batteries and regenerative fuel cells Advancements in ordered membrane electrode assembly (MEA) for water electrolysis Artificial protective layers of zinc metal anodes for reversible aqueous zinc ion batteries The chemical effect of a selenium atom on the catalytic site of precious metals
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