用高温模板法制备的掺杂铽和改性镍的介孔硅胶催化剂用于芳香烃加氢反应

IF 0.5 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY International Journal of Self-Propagating High-Temperature Synthesis Pub Date : 2024-03-14 DOI:10.3103/S1061386224010096
A. A. Tokranov, E. O. Tokranova, R. V. Shafigulin, A. V. Bulanova, M. V. Kuznetsov, A. V. Safonov, Yu. G. Morozov
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引用次数: 0

摘要

摘要 研究了高温模板法制备的掺铽和镍改性介孔二氧化硅凝胶材料的催化性能。通过扫描电子显微镜、X 射线相分析和电感耦合等离子体质谱法研究了所得样品的表面形貌和纹理特征。在温度为 80-170°C 和氢气压力为 3 atm 的条件下,研究了所得催化剂在苯、间二甲苯、对二甲苯和邻二甲苯加氢反应中的催化活性。结果表明,在苯衍生物的加氢反应中,掺入铽元素可提高用镍修饰的催化剂的催化活性。因此,研究表明,掺杂铽元素并用镍修饰的介孔硅胶是苯和二甲苯加氢反应的有效催化剂。
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Catalyst Based on Mesoporous Silica Gel Doped with Terbium and Modified with Nickel Obtained by High-Temperature Template Method for Aromatic Hydrocarbons Hydrogenation

The catalytic properties of materials based on terbium-doped and nickel-modified mesoporous silica gels prepared by the high-temperature template method were studied. The surface morphology and textural characteristics of the obtained samples were studied by scanning electron microscopy, X-ray phase analysis, and inductively coupled plasma mass spectrometry. The catalytic activity of the obtained catalysts was studied in the hydrogenation reaction of benzene, m-, p-, and o-xylene in the temperature range of 80–170°C and at a hydrogen pressure of 3 atm. It was established that doping with terbium leads to an increase in the catalytic activity of the catalyst modified with nickel in the hydrogenation reaction of benzene derivatives. Therefore, it was shown that mesoporous silica gel doped with terbium and modified with nickel is an effective catalyst for the hydrogenation of benzene and xylenes.

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来源期刊
CiteScore
1.00
自引率
33.30%
发文量
27
期刊介绍: International Journal of Self-Propagating High-Temperature Synthesis  is an international journal covering a wide range of topics concerned with self-propagating high-temperature synthesis (SHS), the process for the production of advanced materials based on solid-state combustion utilizing internally generated chemical energy. Subjects range from the fundamentals of SHS processes, chemistry and technology of SHS products and advanced materials to problems concerned with related fields, such as the kinetics and thermodynamics of high-temperature chemical reactions, combustion theory, macroscopic kinetics of nonisothermic processes, etc. The journal is intended to provide a wide-ranging exchange of research results and a better understanding of developmental and innovative trends in SHS science and applications.
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