粗晶白云岩的表征

IF 0.6 4区 工程技术 Q4 ENERGY & FUELS Chemistry and Technology of Fuels and Oils Pub Date : 2024-03-19 DOI:10.1007/s10553-024-01669-y
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引用次数: 0

摘要

中粗晶白云岩是白云岩的一个主要变种,其晶体内外结构的异质性使其成为研究白云岩成因、流体演化和元素迁移的理想载体。本文通过岩石学、阴极发光和相关地球化学方法,对鄂尔多斯盆地下统马家沟组第五段的中粗晶白云岩进行了系统研究。该岩石在泥质粉晶白云岩和粒状白云岩的背景下发育,具有明显的环带结构、萤石和石英互生。与其他白云岩相比,它具有铁、锰富集,Na、Sr含量低,δEu负异常和δ18 O强负偏移的特点。结合成岩演化历史,认为中粗晶白云岩是早期白云石化-大气淡水淋溶-二次埋藏重结晶-深埋溶解等一系列成岩作用的最终产物。电子微探针分析揭示了晶体内外结构和成分的异质性。中粗晶白云石的形成与铁锰含量增加、锰/锶比值上升、锶含量下降以及 Na 浓度先升后降有关。这项研究为进一步研究中粗晶白云岩的成因提供了有价值的参考。
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Characterization of the Coarse-Crystalline Dolomite

Medium-coarse-crystalline dolomite is a major variant of dolomite, and its structural heterogeneity inside and outside the crystals makes it an ideal vehicle for studies of dolomite genesis, fluid evolution and elemental migration. In this paper, the medium-coarse crystalline dolomite from the fifth section of the Majiagou Formation of the Lower Ordos Basin was systematically studied by petrographic, cathodoluminescence and related geochemical methods. The rock is developed in the context of mud powder crystal dolomite and granular dolomite, possessing significant ring band structure, fluorite and quartz intergrowth. Compared with other dolomites, it is characterized by Fe and Mn enrichment and low Na and Sr contents, as well as a negative δEu anomaly and a strong negative δ18 O offset. Combined with the evolutionary history of diagenesis, it is believed that the medium-coarse-crystal dolomite is the end product of a series of diagenetic effects such as early dolomitization-atmospheric freshwater leaching-secondary burial recrystallization-deep burial dissolution. Electron microprobe analysis reveals the structural and compositional heterogeneity inside and outside the crystals. The formation of mediumcoarse- crystalline dolomite is associated with an increase in Fe-Mn content, a rise in the Mn/Sr ratio, a decrease in Sr, and a first rise and then a fall in Na concentration. This study provides a valuable reference for further research on the genesis of the medium-coarse crystalline dolomite.

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来源期刊
Chemistry and Technology of Fuels and Oils
Chemistry and Technology of Fuels and Oils 工程技术-工程:化工
CiteScore
0.90
自引率
16.70%
发文量
119
审稿时长
1.0 months
期刊介绍: Chemistry and Technology of Fuels and Oils publishes reports on improvements in the processing of petroleum and natural gas and cracking and refining techniques for the production of high-quality fuels, oils, greases, specialty fluids, additives and synthetics. The journal includes timely articles on the demulsification, desalting, and desulfurizing of crude oil; new flow plans for refineries; platforming, isomerization, catalytic reforming, and alkylation processes for obtaining aromatic hydrocarbons and high-octane gasoline; methods of producing ethylene, acetylene, benzene, acids, alcohols, esters, and other compounds from petroleum, as well as hydrogen from natural gas and liquid products.
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