Junjie Li, Chuang Liu, Zhenlong Jia, Yingchun Ye, Dawei Lan, Wei Meng, Jianqiang Wang, Zhendong Wang, Yongfeng Hu, Weimin Yang
{"title":"金属/沸石双功能催化剂在苯的选择性加氢烷基化过程中的金属尺寸效应","authors":"Junjie Li, Chuang Liu, Zhenlong Jia, Yingchun Ye, Dawei Lan, Wei Meng, Jianqiang Wang, Zhendong Wang, Yongfeng Hu, Weimin Yang","doi":"10.1007/s11705-024-2406-4","DOIUrl":null,"url":null,"abstract":"<div><p>Bifunctional metal/zeolite materials are some of the most suitable catalysts for the direct hydroalkylation of benzene to cyclohexylbenzene. The overall catalytic performance of this reaction is strongly influenced by the hydrogenation, which is dependent on the metal sizes. Thus, systematically investigating the metal size effects in the hydroalkylation of benzene is essential. In this work, we successfully synthesized Ru and Pd nanoparticles on Sinopec Composition Materials No.1 zeolite with various metal sizes. We demonstrated the size-dependent catalytic activity of zeolite-supported Ru and Pd catalysts in the hydroalkylation of benzene, which can be attributed to the size-induced hydrogen spillover capability differences. Our work presents new insights into the hydroalkylation reaction and may open up a new avenue for the smart design of advanced metal/zeolite bi-functional catalysts.\n</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"18 4","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2024-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Metal size effects over metal/zeolite bifunctional catalysts in the selective hydroalkylation of benzene\",\"authors\":\"Junjie Li, Chuang Liu, Zhenlong Jia, Yingchun Ye, Dawei Lan, Wei Meng, Jianqiang Wang, Zhendong Wang, Yongfeng Hu, Weimin Yang\",\"doi\":\"10.1007/s11705-024-2406-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Bifunctional metal/zeolite materials are some of the most suitable catalysts for the direct hydroalkylation of benzene to cyclohexylbenzene. The overall catalytic performance of this reaction is strongly influenced by the hydrogenation, which is dependent on the metal sizes. Thus, systematically investigating the metal size effects in the hydroalkylation of benzene is essential. In this work, we successfully synthesized Ru and Pd nanoparticles on Sinopec Composition Materials No.1 zeolite with various metal sizes. We demonstrated the size-dependent catalytic activity of zeolite-supported Ru and Pd catalysts in the hydroalkylation of benzene, which can be attributed to the size-induced hydrogen spillover capability differences. Our work presents new insights into the hydroalkylation reaction and may open up a new avenue for the smart design of advanced metal/zeolite bi-functional catalysts.\\n</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":571,\"journal\":{\"name\":\"Frontiers of Chemical Science and Engineering\",\"volume\":\"18 4\",\"pages\":\"\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-03-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Frontiers of Chemical Science and Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11705-024-2406-4\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Frontiers of Chemical Science and Engineering","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s11705-024-2406-4","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Metal size effects over metal/zeolite bifunctional catalysts in the selective hydroalkylation of benzene
Bifunctional metal/zeolite materials are some of the most suitable catalysts for the direct hydroalkylation of benzene to cyclohexylbenzene. The overall catalytic performance of this reaction is strongly influenced by the hydrogenation, which is dependent on the metal sizes. Thus, systematically investigating the metal size effects in the hydroalkylation of benzene is essential. In this work, we successfully synthesized Ru and Pd nanoparticles on Sinopec Composition Materials No.1 zeolite with various metal sizes. We demonstrated the size-dependent catalytic activity of zeolite-supported Ru and Pd catalysts in the hydroalkylation of benzene, which can be attributed to the size-induced hydrogen spillover capability differences. Our work presents new insights into the hydroalkylation reaction and may open up a new avenue for the smart design of advanced metal/zeolite bi-functional catalysts.
期刊介绍：
Frontiers of Chemical Science and Engineering presents the latest developments in chemical science and engineering, emphasizing emerging and multidisciplinary fields and international trends in research and development. The journal promotes communication and exchange between scientists all over the world. The contents include original reviews, research papers and short communications. Coverage includes catalysis and reaction engineering, clean energy, functional material, nanotechnology and nanoscience, biomaterials and biotechnology, particle technology and multiphase processing, separation science and technology, sustainable technologies and green processing.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
