含二萜片段的富勒烯衍生物合成动力学研究

IF 0.6 4区工程技术 Q4 ENERGY & FUELS Chemistry and Technology of Fuels and Oils Pub Date : 2024-03-18 DOI:10.1007/s10553-024-01650-9

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引用次数: 0

摘要

文中给出了利用高效液相色谱法合成含有二萜片段的新型富勒烯衍生物的动力学研究结果，以及随后建立的数学模型。利用 Bingel 程序找到了富勒烯环丙烷化的动力学和活化参数，并提出了反应机理。发现最佳的合成条件是含氯的环丙烷化剂略微过量，并在室温下进行反应。

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Kinetic Study of the Synthesis of a Fullerene Derivative Containing a Diterpene Fragment

Results are given for a kinetic study of the synthesis of a new fullerene derivative containing a diterpene fragment obtained using HPLC and subsequent mathematical modelling. Kinetic and activation parameters were found for the cyclopropanation of fullerene using the Bingel procedure and a reaction mechanism was proposed. The optimal synthesis conditions were found to entail a slight excess of a chlorine‑containing cyclopropanation agent and carrying out the reaction at room temperature.

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来源期刊

Chemistry and Technology of Fuels and Oils 工程技术-工程：化工

CiteScore

0.90

自引率

16.70%

发文量

119

审稿时长

1.0 months

期刊介绍： Chemistry and Technology of Fuels and Oils publishes reports on improvements in the processing of petroleum and natural gas and cracking and refining techniques for the production of high-quality fuels, oils, greases, specialty fluids, additives and synthetics. The journal includes timely articles on the demulsification, desalting, and desulfurizing of crude oil; new flow plans for refineries; platforming, isomerization, catalytic reforming, and alkylation processes for obtaining aromatic hydrocarbons and high-octane gasoline; methods of producing ethylene, acetylene, benzene, acids, alcohols, esters, and other compounds from petroleum, as well as hydrogen from natural gas and liquid products.