用于纳米流体能量转换的 MXene 基纳米复合材料:综述

Guoliang Yang, Dan Liu, Weiwei Lei
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摘要

MXenes 是一类新型的二维(2D)材料,因其独特的性能,包括超强的机械强度、导电性和导热性,而备受关注。在合成过程中,MXene 纳米片被带负电荷的末端基团(如 =O、-OH 和 -F)官能化,从而提高了它们在水和各种有机溶剂中的分散性。得益于这些特性,MXenes 已被广泛研究,并在电池、超级电容器、膜分离和电磁干扰屏蔽等方面表现出卓越的性能。最近,MXenes 在利用可再生能源(如机械能、渗透能、太阳能等)进行纳米流体能量转换方面也引起了广泛关注。基于 MXene 的纳米复合材料具有多样化的结构和更强的性能,在纳米流体能量收集方面显示出巨大的潜力。因此,迫切需要对用于纳米流体能量收集的 MXene 纳米复合材料的最新发展进行综述。本综述将重点关注二维 MXene 纳米复合材料在纳米流体离子传输和能量转换方面的发展。首先,将介绍 MXenes 的基本物理化学特性和合成方法。此外,本综述还将概述 MXene 纳米复合材料的设计及其各种应用。最后,本综述将探讨基于 MXene 的纳米复合材料在纳米流体能量收集方面的巨大潜力和挑战。
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MXene-based nanocomposites for nanofluidic energy conversion: A review

MXenes, a novel group of two-dimensional (2D) materials, have garnered significant attention due to their unique properties, including exceptional mechanical strength and electrical and thermal conductivity. During their synthesis, MXene nanosheets are functionalized with negatively charged terminal groups such as =O, –OH, and –F, which enhance their dispersibility in both water and various organic solvents. Thanks to these characteristics, MXenes have been widely investigated and they demonstrated superior performance in batteries, supercapacitors, membrane separation and electromagnetic interference shielding. More recently, MXenes also attracted much attention in nanofluidic energy conversion from renewable energy sources, such as mechanical force, osmotic energy, solar energy and so on. MXene-based nanocomposites, boasting diverse structures and enhanced properties, show great potential for nanofluidic energy harvesting. Therefore, there is an urgent need for a review to recap recent developments in MXene nanocomposites for nanofluidic energy harvesting. This review will focus on the development of 2D MXene-based nanocomposites for nanofluidic ion transport and energy conversion. Firstly, the fundamental physicochemical properties and synthesis of MXenes will be presented. Furthermore, this review will provide an overview of the design of MXene nanocomposites and their various applications. Finally, this review will explore the promising potential and challenges of MXene-based nanocomposites in nanofluidic energy harvesting.

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