Yu. V. Bilichenko, Pham Van Thuan, D. V. Onuchin, R. S. Borisov, I. B. Sokol’skaya, V. V. Kireev
{"title":"功能减弱的新型环氧-芳氧基环三磷酸嗪","authors":"Yu. V. Bilichenko, Pham Van Thuan, D. V. Onuchin, R. S. Borisov, I. B. Sokol’skaya, V. V. Kireev","doi":"10.1134/s1560090424600141","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>Mixed hydroxy-aryloxy cyclotriphosphazenes have been synthesized via the interaction of hexachlorocyclotriphosphazene with a mixture of 4-allyl-2-methoxyphenol and diphenylolpropane (molar ratio 3.5 : 7.0). Their subsequent epoxidation with epichlorohydrin has afforded phosphazene-containing oligoepoxides with the phosphazene fraction of 50%. Optimal conditions for the synthesis of the composition-uniform phosphazene-containing oligoepoxides bearing one, two, and three epoxide groups in the phosphazene cycle have been elaborated. Such phosphazene-containing oligoepoxides can be cured with the curing agents common for the epoxy resins, to afford self-extinguishing compositions.</p>","PeriodicalId":739,"journal":{"name":"Polymer Science, Series B","volume":null,"pages":null},"PeriodicalIF":1.0000,"publicationDate":"2024-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Novel Epoxy-Aryloxy Cyclotriphosphazenes with Reduced Functionality\",\"authors\":\"Yu. V. Bilichenko, Pham Van Thuan, D. V. Onuchin, R. S. Borisov, I. B. Sokol’skaya, V. V. Kireev\",\"doi\":\"10.1134/s1560090424600141\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<h3 data-test=\\\"abstract-sub-heading\\\">Abstract</h3><p>Mixed hydroxy-aryloxy cyclotriphosphazenes have been synthesized via the interaction of hexachlorocyclotriphosphazene with a mixture of 4-allyl-2-methoxyphenol and diphenylolpropane (molar ratio 3.5 : 7.0). Their subsequent epoxidation with epichlorohydrin has afforded phosphazene-containing oligoepoxides with the phosphazene fraction of 50%. Optimal conditions for the synthesis of the composition-uniform phosphazene-containing oligoepoxides bearing one, two, and three epoxide groups in the phosphazene cycle have been elaborated. Such phosphazene-containing oligoepoxides can be cured with the curing agents common for the epoxy resins, to afford self-extinguishing compositions.</p>\",\"PeriodicalId\":739,\"journal\":{\"name\":\"Polymer Science, Series B\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.0000,\"publicationDate\":\"2024-03-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Science, Series B\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://doi.org/10.1134/s1560090424600141\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series B","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1134/s1560090424600141","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Novel Epoxy-Aryloxy Cyclotriphosphazenes with Reduced Functionality
Abstract
Mixed hydroxy-aryloxy cyclotriphosphazenes have been synthesized via the interaction of hexachlorocyclotriphosphazene with a mixture of 4-allyl-2-methoxyphenol and diphenylolpropane (molar ratio 3.5 : 7.0). Their subsequent epoxidation with epichlorohydrin has afforded phosphazene-containing oligoepoxides with the phosphazene fraction of 50%. Optimal conditions for the synthesis of the composition-uniform phosphazene-containing oligoepoxides bearing one, two, and three epoxide groups in the phosphazene cycle have been elaborated. Such phosphazene-containing oligoepoxides can be cured with the curing agents common for the epoxy resins, to afford self-extinguishing compositions.
期刊介绍：
Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
