调查煤炭自燃引起的烟气对甲烷爆炸风险的影响

Fire Pub Date : 2024-03-22 DOI:10.3390/fire7040105
Sijia Hu, Yanjun Li, Chuanjie Zhu, Baiquan Lin, Qingzhao Li, Baolin Li, Zichao Huang
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摘要

在煤炭自燃(CSC)过程中,会产生大量可燃气体和二氧化碳等惰性气体。然而,之前的研究却令人遗憾地忽略了惰性气体的产生对煤炭自燃过程中甲烷爆炸倾向的关键影响。为了研究 CSC 产生的同时含有可燃气体和惰性气体的烟气环境对甲烷爆炸风险的影响,我们采用了 CSC 高温程序加热试验系统来分析烟气的产生模式。结果发现,在 CSC 过程中会持续产生大量 CO、CO2 和 CH4,它们是 CSC 烟气的主要成分。测试了烟气浓度和组分比(CCO2/CCO)对甲烷爆炸极限的影响。结果发现,CSC 烟气导致甲烷爆炸极限下降,爆炸极限范围在 0 < CCO2/CCO < 0.543 时得到促进,而在 CCO2/CCO > 0.543 时受到抑制。随着 CSC 温度的升高,甲烷爆炸的风险最初受到抑制。当煤炭温度超过 330~410 ℃ 时,爆炸风险迅速扩大。
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Investigating the Influence of Flue Gas Induced by Coal Spontaneous Combustion on Methane Explosion Risk
During the process of coal spontaneous combustion (CSC), a plethora of combustible gases alongside inert gases, such as CO2, are copiously generated. However, prior investigations have regrettably overlooked the pivotal influence of inert gas production on the propensity for methane explosions during CSC. To investigate the impact of the flue gas environment generated by CSC, containing both combustible and inert gases, on the risk of methane explosion, a high-temperature programmed heating test system for CSC was employed to analyze the generation pattern of flue gas. It was found that CO, CO2, and CH4 were continuously generated in large quantities during the process of CSC, which are the main components of CSC flue gas. The effect of the concentration and component ratio (CCO2/CCO) of the flue gas on the methane explosion limit was tested. It was found that the CSC flue gas led to a decrease in the methane explosion limit, and that the explosion limit range was facilitated at 0 < CCO2/CCO < 0.543 and suppressed at CCO2/CCO > 0.543. As the temperature of CSC increases, the risk of methane explosion is initially suppressed. When the coal temperature exceeds 330~410 °C, the explosion risk rapidly expands.
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