用于聚变磁铁的氰酸盐/环氧树脂固化行为分析

Baoleer Baoleer, Yue Xiang, Li Shi, Wen Tao Sun, Zhi Xiong Wu, Rong Jin Huang, Lai Feng Li
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摘要

国际热核聚变实验堆中频线圈和德国 WX-7 恒星模拟聚变反应堆都使用氰酸酯/环氧树脂作为其绝缘结构的基体材料。主要原因是氰酸酯/环氧树脂绝缘材料具有低温力学性能和抗辐射性能,流变性能极低,适用期长。然而,两者混合时会发生高能聚合,释放出大量热量。本研究使用不同的模具制备氰酸酯/环氧树脂(质量比为 4:6),并使用 DSC(差示量热扫描)热分析仪和温度监测仪研究氰酸酯改性环氧树脂基材料的固化行为和热稳定性。经过多次优化,树脂在可控范围内完全固化,玻璃化转变温度在调整前后没有明显变化。
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Analysis of the Curing Behavior of Cyanate/Epoxy Resins for Fusion Magnets
ITER IF coils and the German WX-7 star simulator fusion reactor both use cyanate ester/epoxy resin as the matrix material for their insulation structure. The main reason is that cyanate ester/epoxy resin insulation materials have low-temperature mechanics and radiation resistance, and have extremely low rheological properties and long applicability periods. However, high-energy polymerization will occur when the two are mixed, releasing a huge amount of heat. This study used different molds to prepare cyanate ester/epoxy resin (mass ratio 4:6), and used DSC (Differential Calorimetry Scanning) thermal analyzer and temperature monitoring to study the curing behavior and thermal stability of cyanate ester-modified epoxy resin-based materials. After multiple optimizations, the resin was completely cured within a controllable range, and there was no significant change in the glass transition temperature before and after adjustment.
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