用于液体储存容器的氧氟化聚对苯二甲酸乙二醇酯

V. A. Zakharova, E. D. Nikishin, A. V. Dedov
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引用次数: 0

摘要

我们研究了用氟和氧的混合物对聚对苯二甲酸乙二醇酯进行表面改性以降低其对水和乙醇水溶液的渗透性的效果。我们发现改性后的薄膜对水和乙醇溶液的渗透系数有所降低,而渗透系数的降低程度取决于液体的化学成分。与原始薄膜相比,氧氟化导致生成的改性薄膜的液体扩散系数增大,这与局部缺陷的形成有关,原子力显微镜的显微照片以及原始薄膜和改性薄膜表面粗糙度的测量证实了这一点。
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Oxyfl uorinated polyethylene terephthalate for liquid storage containers
The effectiveness of surface modification of polyethylene terephthalate with a mixture of fluorine and oxygen to reduce the permeability to water and aqueous ethanol solutions has been studied. We obtained a decrease in the permeability coefficient of the modified fi lm for water and ethanol solutions, the degree of decrease in the permeability coefficient depends on the chemical composition of the liquid. Oxyfluorination leads to the production of a modified fi lm with an increased liquid diffusion coefficient compared to the original fi lm, which is associated with the formation of local defects which is confirmed by micrographs made with of an atomic force microscope and by measuring the surface roughness of the original and modified films.
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