将油麻骨热加工成活性炭

Rushan G. Safin, Victor Georgievich Sotnikov
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摘要

亚麻屑是纺织业在对亚麻进行初级加工时产生的废弃物,占油亚麻茎秆总重量的 70%。本文介绍了在 400-650 °C 温度范围内采用缓慢传导热解方法对油亚麻篝火进行热处理的实验研究结果。介绍了亚麻火热分解和过热水蒸气活化残碳的实验台。确定了热解所需的温度范围为 500-600 ℃。对亚麻火热成分解获得的生物炭实验样品的物理化学特性进行了分析。在 400-430 °C 的低温条件下,碳的比重在 80-82% 之间。在 500-600 °C 的温度条件下,碳的比重为 91-93%。在较高温度条件下,气态产物的产量增加,固态碳质残渣中的灰分含量增加。亚麻火灾生物炭的蒸汽活化模式已经确定,因此要达到最佳吸附值,水蒸气的温度应为 900 ℃。实验中获得的活性炭与 BAU-A 活性炭的吸附能力进行了对比分析。根据获得的数据得出结论,亚麻燃烧产生的活性炭符合 GOST 6217-74 的参数要求。
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THERMAL PROCESSING OF OIL FLAX BONES INTO ACTIVATED CARBON
Flax shives – waste generated during the primary processing of flax in the textile industry, make up 70% of the total mass of oil flax stalks. The results of an experimental study of the thermal processing of oil flax bonfires by the method of slow conductive pyrolysis in the temperature range of 400–650 °C are presented. An experimental bench for thermal decomposition of flax fire and activation of carbon residue by superheated water vapor is presented. The required temperature regimes of pyrogenetic decomposition were established, which are in the range of 500–600 °C. An analysis of the physicochemical properties of experimental samples of biochar obtained by pyrogenetic decomposition of flax fires has been carried out. At low temperatures of 400–430 °C, the specific gravity of carbon is in the range of 80–82%. Under temperature conditions of 500–600 °C, the specific gravity of carbon was 91–93%. At higher temperature conditions, the yield of gaseous products increases, and the ash content in the solid carbonaceous residue increases. The modes of steam activation of biochar from flax fires have been established, so to achieve the best sorption values, water vapor should be at a temperature of 900 °C. A comparative analysis of the sorption abilities of experimentally obtained activated carbon with BAU-A activated carbon is given. Based on the data obtained, it was concluded that the activated carbon from the fire of flax corresponds to the parameters of GOST 6217-74.
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