格索高岭土矿床用于生产白云母的成分和耐候性指数

Hassan Aliyu, A. K. Mohammed, S. A. KofarBai, K. R. Muhammad
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摘要

高岭土是一种自然分布于地壳中的铝硅酸盐矿物,由富长石岩石风化形成。格索高岭土矿床对生产水青石的成分要求进行了研究。这些高岭土矿床位于尼日利亚西北部基底复合体的流纹岩中。研究人员从不同深度的五个地点各采集了三个样本,并使用自由膨胀比(FSR)、自由膨胀指数(FSI)、X 射线荧光光谱仪(XRF)和扫描电子显微镜/电子分散 X 射线光谱仪(SEM/EDS)进行了分析。FSI和FSR介于0-6-0.9和16-36之间,显示出非膨胀性和非扩张性高岭土材料。XRF 结果显示,SiO2+ Al2O3+Fe2O3 的平均浓度分别为:第 1 点(78.99 wt.%);第 2 点(78.62 wt.%);第 3 点(79.14 wt.%);第 4 点(80.10 wt.%)和第 5 点(80.0 wt.%),建议将其归类为 N 灰泥(ASTMC 618)。Fe2O3/MgO与SiO3的对比表明,这些样品属于钙碱性系列,是浅色高岭土矿床的标志。计算得出的风化化学指数(CIA:91.34)、风化化学指数(CIW:98.13)、成分变异指数(CIV:0.29)、硅模量比(SM:1.77)、石灰硅比(LSR:0.14)和铝铁比(AIR:30.0)表明,高岭土的风化强度很高,成熟度高,硅含量高,铝含量适中,铁素体含量较少。所研究的高岭土经选矿去除二氧化钛后,可用于生产水青石。
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COMPOSITIONAL AND WEATHERABILITY INDICES OF GETSO KAOLIN DEPOSITS FOR POZZOLANA PRODUCTION
Kaolin is an aluminio-silicate mineral naturally distributed within the earth’s crust formed from the weathering of rich feldspartic rocks. The compositional requirements of Getso kaolin deposits for pozzolana production have been carried out. The kaolin deposits were hosted by the rhyolitic rocks of the basement complex of North-Western Nigeria. Three samples from each five locations at different depths were collected and analysed using Free Swelling Ratio (FSR), Free Swelling Index (FSI), X-Ray Fluorescence Spectrometry (XRF) and Scanning Electron Microscopy/Electron Dispersive X-Ray spectroscopy (SEM/EDS). The FSI and FSR ranged between 0-6-0.9 and 16-36 revealing non-swelling and non-expansive Kaolinitic material. The XRF results showed the average concentration of SiO2+ Al2O3+Fe2O3: point 1 (78.99 wt.%); point 2 (78.62 wt.%); point 3 (79.14 wt.%); point 4 (80.10 wt.%) and point 5 (80.0 wt.%) suggested to be classified as N pozzolana (ASTMC 618). The Fe2O3/MgO versus SiO3 indicated the samples were products of the calc-alkaline series which is an indication of light colour kaolin deposits. The computed Chemical Index of Alteration (CIA: 91.34), Chemical Index of Weatheribility (CIW: 98.13), Index of compositional variability (CIV: 0.29), Silica Modulus Ratio (SM: 1.77), Lime Silica Ratio (LSR: 0.14) and Aluminum Iron Ratio (AIR: 30.0) indicated very strong weathering intensity high matured, high silica moderate aluminum and less ferrite. The studied kaolin could be utilized for the production of pozzolana after its being beneficiated to remove the TiO2.
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