{"title":"黄芩属的新黄酮类化合物。II.黄芩中的黄芩素和黄芩苷","authors":"D. N. Olennikov, N. K. Chirikova","doi":"10.1007/s10600-024-04294-7","DOIUrl":null,"url":null,"abstract":"<p>New glycosides of baicalein (<b>1–4</b>) and wogonin (<b>5</b> and <b>6</b>) were found by studying phenolic compounds from roots of <i>Scutellaria baicalensis</i> Georgi (Lamiaceae) grown with treatment by 24-epibrassinolide. The new compounds were baicalein 7-O-(2′′-O-<i>β</i>-D-glucosyl)-<i>β</i>-D-glucuronopyranoside (scutellariside III, <b>1</b>), baicalein 6-O-<i>β</i>-D-glucopyranoside-7-O-(2′′-O-<i>β</i>-D-glucosyl)-<i>β</i>-D-glucoronopyranoside (scutellariside IV, <b>2</b>), baicalein 6-O-<i>β</i>-D-glycopyranosyl-7-O-<i>β</i>-D-glucuronopyranoside (scutellariside V, <b>3</b>), baicalein 7-O-(2′′-O-malonyl)-<i>β</i>-D-glucuronopyranoside (scutellariside VI, <b>4</b>), wogonin 7-O-(2′′-O-<i>β</i>-D-glucosyl)-<i>β</i>-D-glucuronopyranoside (scutellariside VII, <b>5</b>), and wogonin 7-O-(2′′-O-malonyl)-<i>β</i>-D-glucuronopyranoside (scutellariside VIII, <b>5</b>) according to UV and NMR spectroscopic and mass spectrometric data.</p>","PeriodicalId":514,"journal":{"name":"Chemistry of Natural Compounds","volume":null,"pages":null},"PeriodicalIF":0.8000,"publicationDate":"2024-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"New Flavonoids of the Genus Scutellaria. II. Baicalein and Wogonin Glycosides from S. baicalensis\",\"authors\":\"D. N. Olennikov, N. K. Chirikova\",\"doi\":\"10.1007/s10600-024-04294-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>New glycosides of baicalein (<b>1–4</b>) and wogonin (<b>5</b> and <b>6</b>) were found by studying phenolic compounds from roots of <i>Scutellaria baicalensis</i> Georgi (Lamiaceae) grown with treatment by 24-epibrassinolide. The new compounds were baicalein 7-O-(2′′-O-<i>β</i>-D-glucosyl)-<i>β</i>-D-glucuronopyranoside (scutellariside III, <b>1</b>), baicalein 6-O-<i>β</i>-D-glucopyranoside-7-O-(2′′-O-<i>β</i>-D-glucosyl)-<i>β</i>-D-glucoronopyranoside (scutellariside IV, <b>2</b>), baicalein 6-O-<i>β</i>-D-glycopyranosyl-7-O-<i>β</i>-D-glucuronopyranoside (scutellariside V, <b>3</b>), baicalein 7-O-(2′′-O-malonyl)-<i>β</i>-D-glucuronopyranoside (scutellariside VI, <b>4</b>), wogonin 7-O-(2′′-O-<i>β</i>-D-glucosyl)-<i>β</i>-D-glucuronopyranoside (scutellariside VII, <b>5</b>), and wogonin 7-O-(2′′-O-malonyl)-<i>β</i>-D-glucuronopyranoside (scutellariside VIII, <b>5</b>) according to UV and NMR spectroscopic and mass spectrometric data.</p>\",\"PeriodicalId\":514,\"journal\":{\"name\":\"Chemistry of Natural Compounds\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2024-03-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry of Natural Compounds\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10600-024-04294-7\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MEDICINAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry of Natural Compounds","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10600-024-04294-7","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MEDICINAL","Score":null,"Total":0}
New Flavonoids of the Genus Scutellaria. II. Baicalein and Wogonin Glycosides from S. baicalensis
New glycosides of baicalein (1–4) and wogonin (5 and 6) were found by studying phenolic compounds from roots of Scutellaria baicalensis Georgi (Lamiaceae) grown with treatment by 24-epibrassinolide. The new compounds were baicalein 7-O-(2′′-O-β-D-glucosyl)-β-D-glucuronopyranoside (scutellariside III, 1), baicalein 6-O-β-D-glucopyranoside-7-O-(2′′-O-β-D-glucosyl)-β-D-glucoronopyranoside (scutellariside IV, 2), baicalein 6-O-β-D-glycopyranosyl-7-O-β-D-glucuronopyranoside (scutellariside V, 3), baicalein 7-O-(2′′-O-malonyl)-β-D-glucuronopyranoside (scutellariside VI, 4), wogonin 7-O-(2′′-O-β-D-glucosyl)-β-D-glucuronopyranoside (scutellariside VII, 5), and wogonin 7-O-(2′′-O-malonyl)-β-D-glucuronopyranoside (scutellariside VIII, 5) according to UV and NMR spectroscopic and mass spectrometric data.
期刊介绍：
Chemistry of Natural Compounds publishes reviews and general articles about the structure of different classes of natural compounds, the chemical characteristics of botanical families, genus, and species, to establish the comparative laws and connection between physiological activity and the structure of substances.
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