电动汽车电池缩比模型热失控熄灭实验

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-03-28 DOI:10.1007/s12239-024-00065-z
Hie Chan Kang
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引用次数: 0

摘要

本研究旨在确定一种通过在电池箱内直接通水来抑制电动汽车热失控的方法。我们使用一个由六个 18650 电池组成的锂离子电池组进行了缩减模型实验,该电池组的容量约等于电动汽车充电容量的千分之一。利用冷却方法、热失控阶段和充电状态的简单模型,测量了发热率、传热系数和冷却时间常数。在自然冷却过程中发生热失控时,电池温度以 116 °C/s 的速度升至 630 °C。通过注水,热失控被迅速抑制,时间常数约为 3 秒,传热系数为 3400 W/m2-K。水有效地防止了连锁爆炸,并阻止了有害气体从电池中排出。研究发现,利用圆柱形电池间隙中积水的潜热很难完全抑制热失控。如果将本研究的实验结果应用于实际车辆,预计可以用大约 170 秒的时间常数和 1 吨水抑制热失控。
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Experiment on Extinguishing Thermal Runaway in a Scaled-Down Model of an Electric Vehicle Battery

This study aimed to determine a method to suppress thermal runaway in electric vehicles by passing water directly inside the battery case. A scaled-down model experiment was conducted using a lithium-ion battery pack consisting of six 18650 cells, which is equal to about one-thousandth of an electric vehicle’s charging capacity. The heat generation rate, heat transfer coefficient, and time constant for cooling were measured using a simple model for the cooling methods, thermal runaway stages, and state of charge. When thermal runaway occurred during natural cooling, the battery temperature rose to 630 °C at a rate of 116 °C/s. Through water injection, the thermal runaway was quickly suppressed with a time constant of about 3 s and a heat transfer coefficient of 3400 W/m2·K. The water effectively prevented chain explosions and kept harmful gases emitted from the batteries. It was found that it is difficult to completely suppress thermal runaway using the latent heat of the stagnant water in the spaces between cylindrical batteries. If the experimental results of this study were to be applied to an actual vehicle, it is expected that thermal runaway could be suppressed with a time constant of about 170 s and 1 ton of water.

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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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