视角主义测试案例:量子化学中的不兼容模型

IF 1.8 3区 化学 Q1 HISTORY & PHILOSOPHY OF SCIENCE Foundations of Chemistry Pub Date : 2024-03-28 DOI:10.1007/s10698-024-09502-4
Hernan Lucas Accorinti, Juan Camilo Martínez González
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引用次数: 0

摘要

建模中的不兼容性不能简单地确定。建模被理解为一种活动,其表征力只能部分地确定,这一事实可能会最大限度地减少不相容模型的假定存在。事实上,有人从透视主义的角度提出,不相容是可以消解的,也就是说,由于表征和建模行为本身的实用性和片面性,不相容变得微不足道或根本就是虚假的。从这个角度看,不相容只能是对建模和表征本质的误解所导致的结果。在这个意义上,为了从根本上从透视主义出发解决这一策略,我们首先需要概述最大透视主义论题,试图找出透视主义可能找到的逃避途径,以便将不相容解释为虚幻的不相容。然后,我们将分析共价键的价键模型和分子模型,并得出结论:用来最小化和/或无视不相容性的劝阻策略证明是徒劳的。
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Test case for perspectivism: incompatible models in quantum chemistry

The incompatibility within the context of modeling cannot be established simpliciter. The fact that modeling is understood as an activity whose representational power can only be partially established, may minimize the supposed existence of incompatible models. Indeed, it is argued from perspectivism that incompatibility can be dissolved, meaning that it becomes trivial or simply false due to the inherently pragmatic and partial nature of the act of representation and modeling. From this perspective, incompatibility can only be a consequence of a misunderstanding of the very nature of modeling and representation In this sense, in order to tackle this strategy at its root from perspectivism, we will first need to outline the maximal perspectivism thesis, attempting to identify the possible escape routes that perspectivism could find in order to explain incompatibility as an illusory incompatibility. Then, we will analyze Valence Bond Model and Molecular Model of covalent bonds, and we will conclude that the dissuasive strategies used to minimize and/or disregard incompatibility prove to be fruitless.

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来源期刊
Foundations of Chemistry
Foundations of Chemistry HISTORY & PHILOSOPHY OF SCIENCE-
自引率
22.20%
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期刊介绍: Foundations of Chemistry is an international journal which seeks to provide an interdisciplinary forum where chemists, biochemists, philosophers, historians, educators and sociologists with an interest in foundational issues can discuss conceptual and fundamental issues which relate to the `central science'' of chemistry. Such issues include the autonomous role of chemistry between physics and biology and the question of the reduction of chemistry to quantum mechanics. The journal will publish peer-reviewed academic articles on a wide range of subdisciplines, among others: chemical models, chemical language, metaphors, and theoretical terms; chemical evolution and artificial self-replication; industrial application, environmental concern, and the social and ethical aspects of chemistry''s professionalism; the nature of modeling and the role of instrumentation in chemistry; institutional studies and the nature of explanation in the chemical sciences; theoretical chemistry, molecular structure and chaos; the issue of realism; molecular biology, bio-inorganic chemistry; historical studies on ancient chemistry, medieval chemistry and alchemy; philosophical and historical articles; and material of a didactic nature relating to all topics in the chemical sciences. Foundations of Chemistry plans to feature special issues devoted to particular themes, and will contain book reviews and discussion notes. Audience: chemists, biochemists, philosophers, historians, chemical educators, sociologists, and other scientists with an interest in the foundational issues of science.
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