在外加磁场、压力和温度条件下,砷化镓固体材料的热力学性质扩展到表面吸附作用

Alemu Gurmessa Gindaba, M. Woldemariam, Senbeto Kena Etana, S. Elangovan
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摘要

这项研究工作全面分析了表面压力、外部磁场和温度等独立参数对统计热力学量自由能、磁化、占据表面分数和平衡长度的影响。我们的研究方法与处理表面参数行为依赖性的理论研究不同。我们的机制是研究两个因变量在两个或多个不同独立参数影响下的相互关系。因此,它看似复杂,但却能以相同的速度探测系统的表面信息。我们研究了热激发效应,这种效应导致与每个被占据表面位点接触的电子气体脱离,从而减少了表面在相反外磁场和压力下的吸附,提高了电子接触表面位点的被占据表面概率。我们的研究结果表明,在外加磁场和压力的影响下,固体砷化镓表面倾向于捕获电子,从而结合电子并产生额外的约束势,同时表面特性也会受到影响。另一方面,表面自由能与磁化率、占据的表面分数成反比关系,在平衡长度的情况下,它取决于强外部磁场。
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Thermodynamic Properties of GaAs Solid Materials Extended to Surface Adsorption under External Magnetic Fields, Pressure, and Temperature
This research work instrumentalizes comprehensively the impacts of independent parameters like surface pressure, external magnetic field, and temperature on statistical thermodynamic quantities free energy, magnetization, occupied surface fraction, and equilibrium length. We approached it differently from a theoretical investigation conducted dealt with the behavioral dependence of surface parameters. Our mechanism was to investigate the interrelation between two dependent variables under exposure to two or more different independent parameters. Thus it seems complicated but it is used to probe surface information from the system at the same pace. We investigated the thermal excitation effect that leads to the detachment of the electron gas in contact with each occupied surface site, which reduces the adsorption of the surface in contrary external magnetic fields and pressure enhances the occupied surface probability of electrons to contact surface sites. Our findings reveal that the solid GaAs surface tends to capture electrons under the influences of external magnetic fields and pressure thus binding electrons and putting additional confining potential meanwhile the surface properties are affected. On the other hand surface, free energy has an inverse relation with magnetization, occupied surface fraction, in the case of equilibrium length it depended on the strong external magnetic fields.
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