首页 > 最新文献

Materials Science Forum最新文献

英文 中文
Increasing Concrete Durability Against Organic Acid Corrosion with Coal Fly Ash and Bagasse Fly Ash as Cement Replacements 用煤粉灰和蔗渣粉灰替代水泥提高混凝土抗有机酸腐蚀的耐久性
Pub Date : 2024-07-18 DOI: 10.4028/p-tm8lwe
Jensak Koschanin, P. Julphunthong
The deterioration of concrete from acid corrosion is a common issue in various industrial and natural environments. To address this problem, coal fly ash and bagasse fly ash were utilized as cement replacements in concrete. This study investigates the effects of these ashes on concrete's ability to withstand organic acid corrosion in depth, including a thorough examination of their chemical compositions, physical properties, and interactions within the concrete matrix. Furthermore, the research involves adjusting the blend proportions to provide exceptional resistance to acid corrosion. The results of the study highlight the significance of coal fly ash and bagasse fly ash in improving concrete's resistance to organic acid corrosion. The use of these materials as cement replacements significantly enhances concrete's resistance to organic acid corrosion, and this improvement becomes more apparent as substitution rates increase. This effect is primarily attributed to increased pozzolanic reactivity, resulting in a reduction in calcium hydroxide concentration within the cement matrix.
在各种工业和自然环境中,混凝土因酸性腐蚀而老化是一个常见问题。为解决这一问题,人们利用粉煤灰和甘蔗渣粉煤灰作为混凝土中的水泥替代品。本研究深入探讨了这些灰烬对混凝土抵御有机酸腐蚀能力的影响,包括对它们的化学成分、物理性质以及在混凝土基质中的相互作用进行全面检查。此外,研究还涉及调整混合比例,以提供优异的耐酸腐蚀性能。研究结果凸显了粉煤灰和甘蔗渣粉煤灰在提高混凝土抗有机酸腐蚀能力方面的重要作用。使用这些材料作为水泥替代品,可显著提高混凝土的抗有机酸腐蚀能力,而且随着替代率的提高,这种提高会变得更加明显。产生这种效果的主要原因是水泥基质中的氢氧化钙浓度降低,从而提高了水泥的反应活性。
{"title":"Increasing Concrete Durability Against Organic Acid Corrosion with Coal Fly Ash and Bagasse Fly Ash as Cement Replacements","authors":"Jensak Koschanin, P. Julphunthong","doi":"10.4028/p-tm8lwe","DOIUrl":"https://doi.org/10.4028/p-tm8lwe","url":null,"abstract":"The deterioration of concrete from acid corrosion is a common issue in various industrial and natural environments. To address this problem, coal fly ash and bagasse fly ash were utilized as cement replacements in concrete. This study investigates the effects of these ashes on concrete's ability to withstand organic acid corrosion in depth, including a thorough examination of their chemical compositions, physical properties, and interactions within the concrete matrix. Furthermore, the research involves adjusting the blend proportions to provide exceptional resistance to acid corrosion. The results of the study highlight the significance of coal fly ash and bagasse fly ash in improving concrete's resistance to organic acid corrosion. The use of these materials as cement replacements significantly enhances concrete's resistance to organic acid corrosion, and this improvement becomes more apparent as substitution rates increase. This effect is primarily attributed to increased pozzolanic reactivity, resulting in a reduction in calcium hydroxide concentration within the cement matrix.","PeriodicalId":507742,"journal":{"name":"Materials Science Forum","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141827072","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Slenderness Limits and Buckling Response of Bamboo Scrimber under Axial Compression 轴向压缩条件下竹制护壁板的纤度极限和屈曲响应
Pub Date : 2024-07-18 DOI: 10.4028/p-nadnw6
J. Goonewardena, M. Ashraf, Mahbube Subhani, B. Kafle, Johannes Reiner
Bamboo scrimber is a promising engineered bamboo material in the construction sector due to its favourable mechanical and aesthetic properties. Although considerable research on mechanical properties has been conducted, there is a gap in the knowledge of slenderness limits for short columns of bamboo scrimber. Slenderness limits suggested in four testing and structural design standards that are commonly used for engineered bamboo have been critically analysed and compared to identify their relative shortcomings. From these standards, Eurocode 5 proposes a better limit while the others behave conservatively. Owing to the lack of a design standard for engineered bamboo, researchers abide by standards compiled for timber/engineered timber to predict the compressive response of intermediate and long columns. In addition to showing the limitations of these studies, a rational column equation has been derived with a modified Euler load that yields reasonable accuracy with respect to two experimental studies.
竹节材因其良好的机械和美学特性,在建筑领域是一种前景广阔的工程竹材。尽管对竹材的力学性能进行了大量研究,但对竹材短柱的纤度极限的认识仍是空白。我们对常用于工程竹材的四种测试和结构设计标准中提出的纤度限值进行了批判性分析和比较,以找出它们的相对缺陷。在这些标准中,欧洲规范 5 提出了一个较好的限值,而其他标准则表现保守。由于缺乏工程竹材的设计标准,研究人员在预测中柱和长柱的抗压响应时遵循了木材/工程木材的标准。除了说明这些研究的局限性外,我们还利用修正的欧拉荷载推导出了一个合理的柱方程,该方程与两项实验研究相比具有合理的准确性。
{"title":"Slenderness Limits and Buckling Response of Bamboo Scrimber under Axial Compression","authors":"J. Goonewardena, M. Ashraf, Mahbube Subhani, B. Kafle, Johannes Reiner","doi":"10.4028/p-nadnw6","DOIUrl":"https://doi.org/10.4028/p-nadnw6","url":null,"abstract":"Bamboo scrimber is a promising engineered bamboo material in the construction sector due to its favourable mechanical and aesthetic properties. Although considerable research on mechanical properties has been conducted, there is a gap in the knowledge of slenderness limits for short columns of bamboo scrimber. Slenderness limits suggested in four testing and structural design standards that are commonly used for engineered bamboo have been critically analysed and compared to identify their relative shortcomings. From these standards, Eurocode 5 proposes a better limit while the others behave conservatively. Owing to the lack of a design standard for engineered bamboo, researchers abide by standards compiled for timber/engineered timber to predict the compressive response of intermediate and long columns. In addition to showing the limitations of these studies, a rational column equation has been derived with a modified Euler load that yields reasonable accuracy with respect to two experimental studies.","PeriodicalId":507742,"journal":{"name":"Materials Science Forum","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141827926","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of the Mechanical Properties of Recycled Coarse Aggregate Concrete against the Action of Fire 评估再生粗骨料混凝土在火灾作用下的力学性能
Pub Date : 2024-07-18 DOI: 10.4028/p-k0uuxp
Andre Jhoel Lamas Chavez, Alvaro Fabrizio Aliaga Guevara, Pablo Jhoel Peña Torres
Growing concerns about sustainability and the search for greener alternatives in construction have led to a renewed interest in recycled concrete as a building material. Recycled concrete is produced using recycled aggregates, such as construction and demolition debris, instead of virgin aggregates, which reduces the demand for natural resources and the accumulation of waste. However, the viability of recycled concrete in high-temperature applications, such as fires or exposure to extremely high temperatures, has come under critical scrutiny. In this study we are going to talk about the differences between conventional concrete and concrete with recycled aggregate after being exposed to high temperatures, we will focus on issues of resistance to compression, traction and modulus of elasticity. We were able to obtain in our tests that the greater the amount of recycled aggregate that we use in the concrete, the lower mechanical properties we obtain with respect to conventional concrete after being exposed to high temperatures, this is due to the adhered mortar that the recycled aggregate presents (in in our case 42% adhered mortar).
人们对可持续发展的关注与日俱增,同时也在寻找更环保的建筑材料,这使人们对再生混凝土这种建筑材料重新产生了兴趣。再生混凝土是利用建筑和拆除废料等再生骨料代替原生骨料生产的,这减少了对自然资源的需求和废物的积累。然而,再生混凝土在火灾或极端高温等高温应用中的可行性受到了严格的审查。在本研究中,我们将讨论传统混凝土和使用再生骨料的混凝土在暴露于高温后的差异,我们将重点讨论抗压性、牵引力和弹性模量等问题。我们在测试中发现,混凝土中使用的再生骨料越多,暴露在高温下后获得的机械性能就会比传统混凝土低,这是由于再生骨料附着了砂浆(在我们的案例中附着了 42% 的砂浆)。
{"title":"Evaluation of the Mechanical Properties of Recycled Coarse Aggregate Concrete against the Action of Fire","authors":"Andre Jhoel Lamas Chavez, Alvaro Fabrizio Aliaga Guevara, Pablo Jhoel Peña Torres","doi":"10.4028/p-k0uuxp","DOIUrl":"https://doi.org/10.4028/p-k0uuxp","url":null,"abstract":"Growing concerns about sustainability and the search for greener alternatives in construction have led to a renewed interest in recycled concrete as a building material. Recycled concrete is produced using recycled aggregates, such as construction and demolition debris, instead of virgin aggregates, which reduces the demand for natural resources and the accumulation of waste. However, the viability of recycled concrete in high-temperature applications, such as fires or exposure to extremely high temperatures, has come under critical scrutiny. In this study we are going to talk about the differences between conventional concrete and concrete with recycled aggregate after being exposed to high temperatures, we will focus on issues of resistance to compression, traction and modulus of elasticity. We were able to obtain in our tests that the greater the amount of recycled aggregate that we use in the concrete, the lower mechanical properties we obtain with respect to conventional concrete after being exposed to high temperatures, this is due to the adhered mortar that the recycled aggregate presents (in in our case 42% adhered mortar).","PeriodicalId":507742,"journal":{"name":"Materials Science Forum","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141824834","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of the Influence of Brick Dust and Rice Husk Ash on the Mechanical and Physical Behavior of a Geopolymeric and Eco-Efficient Concrete with Partial Cement Replacements 评估砖屑和稻壳灰对部分取代水泥的地聚合生态高效混凝土的机械和物理行为的影响
Pub Date : 2024-07-18 DOI: 10.4028/p-louv6n
Sanchez Rosario Ronald Luis, Soto Noa Eder, Karla Lisette Lopez Pasapera
The present research work addresses the issue of development of geopolymers as an alternative to ordinary Portland cement. For which, descriptions of the materials and instruments used for the necessary tests were made. Also, the experimental methodology for the design of geopolymeric concrete was presented, in which the production process of the precursor material and the activating agent is explained. The dosages and how the four types of mixtures to be tested are composed are shown: the standard concrete (CP) and three mixtures with different replacement variables (M1, M2 and M3). In order to study the behavior and influence of brick dust, a mixture was designed with different dosages to replace the cement with the precursor in 80%, 90% and 95% alkalized by sodium hydroxide (NaOH) 12 M and rice husk ash (RHA) with a proportion of 75% - 25%, respectively. The results show that the master concrete cores presented average resistances of up to 26.52 MPa, while with a replacement of 80%, an average of 27.05 MPa was recorded, with 90% an average of 26.05 MPa and with 95%, resistances up to 22.84 MPa after 28 days of testing. These data indicate that geopolymeric concretes with partial replacement maintain acceptable physical and mechanical properties. The specific combination of replacing cement with brick dust and rice husk ash in the alkaline solution results in favorable concrete conditions. This study demonstrates the quantitative viability of using eco-efficient geopolymers with partial cement replacements, offering a more sustainable alternative in construction.
本研究工作涉及开发土工聚合物作为普通硅酸盐水泥替代品的问题。为此,对用于必要测试的材料和仪器进行了说明。此外,还介绍了设计土工聚合物混凝土的实验方法,其中解释了前体材料和活化剂的生产过程。此外,还介绍了四种待测混合物的剂量和组成方式:标准混凝土(CP)和三种具有不同替代变量的混合物(M1、M2 和 M3)。为了研究砖灰的行为和影响,设计了一种不同剂量的混合物,用氢氧化钠(NaOH)12 M 碱化的 80%、90% 和 95%的前驱体以及比例分别为 75% - 25% 的稻壳灰(RHA)替代水泥。结果表明,经过 28 天的测试,主混凝土芯的平均阻力高达 26.52 兆帕,而替代率为 80% 的混凝土芯的平均阻力为 27.05 兆帕,替代率为 90% 的混凝土芯的平均阻力为 26.05 兆帕,替代率为 95% 的混凝土芯的平均阻力为 22.84 兆帕。这些数据表明,部分替代的土工聚合物混凝土能保持可接受的物理和机械性能。在碱性溶液中用砖灰和稻壳灰替代水泥的特定组合可获得良好的混凝土条件。这项研究从数量上证明了使用生态高效的土工聚合物部分替代水泥的可行性,为建筑业提供了一种更具可持续性的替代方案。
{"title":"Evaluation of the Influence of Brick Dust and Rice Husk Ash on the Mechanical and Physical Behavior of a Geopolymeric and Eco-Efficient Concrete with Partial Cement Replacements","authors":"Sanchez Rosario Ronald Luis, Soto Noa Eder, Karla Lisette Lopez Pasapera","doi":"10.4028/p-louv6n","DOIUrl":"https://doi.org/10.4028/p-louv6n","url":null,"abstract":"The present research work addresses the issue of development of geopolymers as an alternative to ordinary Portland cement. For which, descriptions of the materials and instruments used for the necessary tests were made. Also, the experimental methodology for the design of geopolymeric concrete was presented, in which the production process of the precursor material and the activating agent is explained. The dosages and how the four types of mixtures to be tested are composed are shown: the standard concrete (CP) and three mixtures with different replacement variables (M1, M2 and M3). In order to study the behavior and influence of brick dust, a mixture was designed with different dosages to replace the cement with the precursor in 80%, 90% and 95% alkalized by sodium hydroxide (NaOH) 12 M and rice husk ash (RHA) with a proportion of 75% - 25%, respectively. The results show that the master concrete cores presented average resistances of up to 26.52 MPa, while with a replacement of 80%, an average of 27.05 MPa was recorded, with 90% an average of 26.05 MPa and with 95%, resistances up to 22.84 MPa after 28 days of testing. These data indicate that geopolymeric concretes with partial replacement maintain acceptable physical and mechanical properties. The specific combination of replacing cement with brick dust and rice husk ash in the alkaline solution results in favorable concrete conditions. This study demonstrates the quantitative viability of using eco-efficient geopolymers with partial cement replacements, offering a more sustainable alternative in construction.","PeriodicalId":507742,"journal":{"name":"Materials Science Forum","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141825277","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Performance of the Mechanical and Durability Properties of Eco-Friendly Concrete Containing Glass Powder (GP) and Ground Granulated Blast Slag (GGBS) 含玻璃粉(GP)和磨细高炉矿渣(GGBS)的环保混凝土的力学性能和耐久性能
Pub Date : 2024-07-18 DOI: 10.4028/p-s42uur
G. Vasudevan, Shantha Kumari Muniyandi, Gunavathy Kanniyapan, Lim Eng Hock
This study uses varying percentages of glass powder (GP) and ground granulated blast furnace slag (GGBS) as partial replacements for Portland cement to investigate their effects on the behavior of the concrete’s mechanical and durability properties. Due to the adverse environmental impacts of cement manufacturing, there have been efforts to replace cement with supplementary cementitious materials (SCMs) to reduce cement consumption while enhancing concrete performance. This study evaluates the effects of adding varying percentages of silica fume (SF) and ground granulated blast furnace slag (GGBFS) on the mechanical and durability properties of the modified concrete. It also evaluates their compressive, tensile, and flexural strength and conducts the Initial Surface Absorption Test (ISAT), carbonation test, and microstructure analysis using scanning electron microscopy (SEM). The research variables are partial cement replacement with varying percentages of 5%, 10%, 15%, and 20% of different pozzolanic materials. The water-cement ratio in this experiment is 0.53.
本研究使用不同比例的玻璃粉(GP)和磨细高炉矿渣(GGBS)作为硅酸盐水泥的部分替代品,研究它们对混凝土机械性能和耐久性能的影响。由于水泥生产对环境的不利影响,人们一直在努力用胶凝补充材料(SCM)替代水泥,以减少水泥用量,同时提高混凝土性能。本研究评估了添加不同比例的硅灰(SF)和磨细高炉矿渣(GGBFS)对改性混凝土机械性能和耐久性能的影响。研究还评估了它们的抗压、抗拉和抗弯强度,并进行了初始表面吸收试验(ISAT)、碳化试验和使用扫描电子显微镜(SEM)进行的微观结构分析。研究变量为部分水泥替代 5%、10%、15% 和 20% 不同比例的混合材料。本实验中的水灰比为 0.53。
{"title":"Performance of the Mechanical and Durability Properties of Eco-Friendly Concrete Containing Glass Powder (GP) and Ground Granulated Blast Slag (GGBS)","authors":"G. Vasudevan, Shantha Kumari Muniyandi, Gunavathy Kanniyapan, Lim Eng Hock","doi":"10.4028/p-s42uur","DOIUrl":"https://doi.org/10.4028/p-s42uur","url":null,"abstract":"This study uses varying percentages of glass powder (GP) and ground granulated blast furnace slag (GGBS) as partial replacements for Portland cement to investigate their effects on the behavior of the concrete’s mechanical and durability properties. Due to the adverse environmental impacts of cement manufacturing, there have been efforts to replace cement with supplementary cementitious materials (SCMs) to reduce cement consumption while enhancing concrete performance. This study evaluates the effects of adding varying percentages of silica fume (SF) and ground granulated blast furnace slag (GGBFS) on the mechanical and durability properties of the modified concrete. It also evaluates their compressive, tensile, and flexural strength and conducts the Initial Surface Absorption Test (ISAT), carbonation test, and microstructure analysis using scanning electron microscopy (SEM). The research variables are partial cement replacement with varying percentages of 5%, 10%, 15%, and 20% of different pozzolanic materials. The water-cement ratio in this experiment is 0.53.","PeriodicalId":507742,"journal":{"name":"Materials Science Forum","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141825990","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of WO3-Nanoparticles on the Setting Time and Early Strength for Different Cementitious Materials WO3 纳米粒子对不同水泥基材料凝结时间和早期强度的影响
Pub Date : 2024-07-18 DOI: 10.4028/p-kfj0i5
S.M.A. El-Gamal, Mostafa A. Sayed, Alaa Mohsen, M. Hazem, Mona M. Wetwet, F. M. Helmy, M. Ramadan
Generally, the setting time and early strength of the cementitious materials are good indications to identify their suitability to be employed as binding materials. Due to the high surface area of nanomaterials, it is considered one of the optimal solutions to modify these properties. Accordingly, this work is focused on comparing the impact of laboratory-prepared tungsten oxide nanoparticles (WO3-NP) on two cementitious materials: OPC and alkali-activated slag (AAS). The initial/final-setting time and early compressive strength up to 28-days of the OPC and AAS specimens, modified with 1, 2 wt.% WO3-NP, were investigated. The results displayed that WO3-NP has a significant impact on the acceleration of the initial/final-setting time of both binding materials. Moreover, the optimal dosage from WO3-NP (1 wt.%) upgraded the compressive strength by 19.5 and 15.1% for OPC and AAS, respectively after 7 days. The nucleation-seeds and nano-filler effect of WO3-NPs are the focal explanations behind improving these properties via the formation of strength-giving phases and then obtaining a compact microstructure as proved by XRD and SEM.
一般来说,水泥基材料的凝结时间和早期强度是确定其是否适合用作结合材料的良好指标。由于纳米材料具有高表面积,因此被认为是改变这些特性的最佳解决方案之一。因此,这项工作的重点是比较实验室制备的氧化钨纳米颗粒(WO3-NP)对两种胶凝材料的影响:OPC 和碱活性矿渣(AAS)的影响。研究了用 1、2 wt.% WO3-NP 改性的 OPC 和 AAS 试样的初/终凝时间和 28 天的早期抗压强度。结果表明,WO3-NP 对加快两种结合材料的初凝/终凝时间有显著影响。此外,WO3-NP 的最佳用量(1 wt.%)可在 7 天后将 OPC 和 AAS 的抗压强度分别提高 19.5% 和 15.1%。正如 XRD 和 SEM 所证明的那样,WO3-NP 的成核种子和纳米填料效应是通过形成赋予强度的相并获得致密的微观结构来改善这些性能的主要原因。
{"title":"Impact of WO3-Nanoparticles on the Setting Time and Early Strength for Different Cementitious Materials","authors":"S.M.A. El-Gamal, Mostafa A. Sayed, Alaa Mohsen, M. Hazem, Mona M. Wetwet, F. M. Helmy, M. Ramadan","doi":"10.4028/p-kfj0i5","DOIUrl":"https://doi.org/10.4028/p-kfj0i5","url":null,"abstract":"Generally, the setting time and early strength of the cementitious materials are good indications to identify their suitability to be employed as binding materials. Due to the high surface area of nanomaterials, it is considered one of the optimal solutions to modify these properties. Accordingly, this work is focused on comparing the impact of laboratory-prepared tungsten oxide nanoparticles (WO3-NP) on two cementitious materials: OPC and alkali-activated slag (AAS). The initial/final-setting time and early compressive strength up to 28-days of the OPC and AAS specimens, modified with 1, 2 wt.% WO3-NP, were investigated. The results displayed that WO3-NP has a significant impact on the acceleration of the initial/final-setting time of both binding materials. Moreover, the optimal dosage from WO3-NP (1 wt.%) upgraded the compressive strength by 19.5 and 15.1% for OPC and AAS, respectively after 7 days. The nucleation-seeds and nano-filler effect of WO3-NPs are the focal explanations behind improving these properties via the formation of strength-giving phases and then obtaining a compact microstructure as proved by XRD and SEM.","PeriodicalId":507742,"journal":{"name":"Materials Science Forum","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141826047","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing Mechanical Properties with Water Hyacinth Fiber-Reinforced Bio-Based Epoxy Composites 用布袋莲纤维增强生物基环氧树脂复合材料提高机械性能
Pub Date : 2024-07-18 DOI: 10.4028/p-7acvsi
Naruemon Sumrith, Nipon Bhuwakiatkhamjorn, Kittipat Keawked, Paweenvat Iamim, Chakaphan Ngaowthong
The purpose of this research is to examine how the size and quantity of water hyacinth (WH) fibers impact their reinforcement of bio-based epoxy resin, with a specific focus on how these factors influence mechanical properties. The study involves utilizing specimens containing WH fiber particle sizes of 100 µm and 500 µm, combined with varying proportions of 10%, 20%, and 30% by volume. The application of sodium hydroxide (NaOH) as a chemical treatment for the fibers enhances the mechanical characteristics of the composite. The results indicate that the tensile modulus of 30WH100 exceeds that of neat epoxy by roughly 17.6%. Noteworthy is the hardness value of 10WH100 at 99.73 HRL, compared to the value of 99.98 HRL seen in neat epoxy. This implies minor differences in hardness properties across the obtained results.
本研究旨在探讨布袋莲(WH)纤维的尺寸和数量如何影响其对生物基环氧树脂的增强作用,重点关注这些因素如何影响机械性能。研究使用的试样含有 100 微米和 500 微米的布袋莲纤维颗粒,以及 10%、20% 和 30%(按体积计算)的不同比例。应用氢氧化钠(NaOH)对纤维进行化学处理可增强复合材料的机械特性。结果表明,30WH100 的拉伸模量比纯环氧树脂高出约 17.6%。值得注意的是,10WH100 的硬度值为 99.73 HRL,而纯环氧的硬度值为 99.98 HRL。这意味着所获得的结果在硬度特性上存在细微差别。
{"title":"Enhancing Mechanical Properties with Water Hyacinth Fiber-Reinforced Bio-Based Epoxy Composites","authors":"Naruemon Sumrith, Nipon Bhuwakiatkhamjorn, Kittipat Keawked, Paweenvat Iamim, Chakaphan Ngaowthong","doi":"10.4028/p-7acvsi","DOIUrl":"https://doi.org/10.4028/p-7acvsi","url":null,"abstract":"The purpose of this research is to examine how the size and quantity of water hyacinth (WH) fibers impact their reinforcement of bio-based epoxy resin, with a specific focus on how these factors influence mechanical properties. The study involves utilizing specimens containing WH fiber particle sizes of 100 µm and 500 µm, combined with varying proportions of 10%, 20%, and 30% by volume. The application of sodium hydroxide (NaOH) as a chemical treatment for the fibers enhances the mechanical characteristics of the composite. The results indicate that the tensile modulus of 30WH100 exceeds that of neat epoxy by roughly 17.6%. Noteworthy is the hardness value of 10WH100 at 99.73 HRL, compared to the value of 99.98 HRL seen in neat epoxy. This implies minor differences in hardness properties across the obtained results.","PeriodicalId":507742,"journal":{"name":"Materials Science Forum","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141827705","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Carbon Fiber/Epoxy Vitrimer Composite Material for Pressure Vessels: Towards Development of Sustainable Materials 用于压力容器的碳纤维/环氧树脂 Vitrimer 复合材料:开发可持续材料
Pub Date : 2024-07-18 DOI: 10.4028/p-dzac8g
Sudhanshu Nartam, Sandip Budhe, Jinu Paul
The main aim of the research work is to develop a sustainable vitrimer composite that can be easily recyclable and reusable carbon fibre for secondary applications. Vitrimer materials provide opportunities for recycle thermosets and CFRP composites, however, the retained properties of composite still limit their applications. In this research work, the focus is to investigate material properties of vitamer/carbon fiber composite and the retained properties after recycling of the same. A vitrimer material has been developed using an epoxy (EP) matrix and bio-based curing agent and citric acid (CA), and finally reinforced with carbon fibre. The vitrimer materials were prepared with varying ratios of acid to the epoxy ratio between 0.30 and 0.40 to prepare the best performance vitrimer. Fourier transform infrared (FTIR) spectrometry was conducted in Transmittance mode over a range of wavelengths from 400 to 4000 cm-1. The mechanical testing carried out at room temperature under tensile loading. Results found that the Vitrimer composite could be effectively dissolved in DMF, enabling the recovery of the carbon fibers. The results of the study indicate that the EP/CA vitrimers exhibit thermomechanical properties that are comparable to those of the epoxy vitrimer cured using a petroleum-based curing agent. The most important results that demonstrate the use of EP/CA vitrimers may be a promising alternative to traditional epoxy composites in various applications.
这项研究工作的主要目的是开发一种可持续的玻璃纤维复合材料,这种材料可以很容易地回收和再利用碳纤维,用于二次应用。三聚氰胺材料为热固性塑料和 CFRP 复合材料的循环利用提供了机会,但复合材料的保留特性仍然限制了其应用。在这项研究工作中,重点是研究玻璃纤维/碳纤维复合材料的材料特性以及回收后的保留特性。使用环氧树脂(EP)基体、生物基固化剂和柠檬酸(CA)开发了一种玻璃基复合材料,最后用碳纤维进行增强。制备玻璃rimer 材料时,酸与环氧树脂的比例在 0.30 和 0.40 之间,以制备出性能最佳的玻璃rimer。傅立叶变换红外线(FTIR)光谱分析采用透射模式,波长范围为 400 至 4000 cm-1。在室温下进行了拉伸负荷下的机械测试。结果发现,Vitrimer 复合材料可在 DMF 中有效溶解,从而使碳纤维得以回收。研究结果表明,EP/CA 玻璃rimer 的热机械性能与使用石油基固化剂固化的环氧玻璃rimer 相当。最重要的结果表明,在各种应用中,使用 EP/CA 玻璃rimers 可以替代传统的环氧树脂复合材料。
{"title":"Carbon Fiber/Epoxy Vitrimer Composite Material for Pressure Vessels: Towards Development of Sustainable Materials","authors":"Sudhanshu Nartam, Sandip Budhe, Jinu Paul","doi":"10.4028/p-dzac8g","DOIUrl":"https://doi.org/10.4028/p-dzac8g","url":null,"abstract":"The main aim of the research work is to develop a sustainable vitrimer composite that can be easily recyclable and reusable carbon fibre for secondary applications. Vitrimer materials provide opportunities for recycle thermosets and CFRP composites, however, the retained properties of composite still limit their applications. In this research work, the focus is to investigate material properties of vitamer/carbon fiber composite and the retained properties after recycling of the same. A vitrimer material has been developed using an epoxy (EP) matrix and bio-based curing agent and citric acid (CA), and finally reinforced with carbon fibre. The vitrimer materials were prepared with varying ratios of acid to the epoxy ratio between 0.30 and 0.40 to prepare the best performance vitrimer. Fourier transform infrared (FTIR) spectrometry was conducted in Transmittance mode over a range of wavelengths from 400 to 4000 cm-1. The mechanical testing carried out at room temperature under tensile loading. Results found that the Vitrimer composite could be effectively dissolved in DMF, enabling the recovery of the carbon fibers. The results of the study indicate that the EP/CA vitrimers exhibit thermomechanical properties that are comparable to those of the epoxy vitrimer cured using a petroleum-based curing agent. The most important results that demonstrate the use of EP/CA vitrimers may be a promising alternative to traditional epoxy composites in various applications.","PeriodicalId":507742,"journal":{"name":"Materials Science Forum","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141826745","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Blending Constant Concentration of Acrylic Polymer with Varying Amount of Fly Ash to the Permeability and Strength of Large Aggregate Pervious Concrete 将恒定浓度的丙烯酸聚合物与不同用量的粉煤灰混合对大骨料透水混凝土的渗透性和强度的影响
Pub Date : 2024-07-18 DOI: 10.4028/p-eckdy1
Hermie M. Del Pilar, Carlo B. Caballero, Mike Edson T. Milano, Nikko San C. Quimio
Storm water runoff brings environmental problems like flooding and pollutant transport, not only to the residential areas but also in low elevated roads with poor to bad sewage system. Soil is a naturally porous material, and its permeable property is blocked as surface pavements are constructed, making pervious concrete an important alternative in addressing the problem caused by storm water runoff. In this study, a constant weight percentage of 15% acrylic polymer (AcP) solution on water is used for the preparation of concrete mix, resulted to an increase in strength of the PC. Another additive which is the Fly ash (FA) was used to enhance the strength of the PC partially replacing the Type I cement at 5%, 10%, 15%, and 20%. Physical (porosity and permeability) and mechanical (compression and flexural strength) properties were investigated, and the statistical tool One-Way Analysis of Variance (ANOVA) was used to analyze the results. The 20% replacement obtained the highest compressive strength at 9.89MPa, while the 15% replacement acquired the highest flexural strength at 3.57 MPa. In terms of permeability, the control mix (0% Fly ash) has the highest performance at 4.76 cm/s. The favorable result in pervious concrete proved that the use of Acrylic Polymer and fly ash blend to the cement were a useful component to further improve its mechanical properties, and acceptability of its use for flood and contaminant transport mitigation.
雨水径流不仅给居民区带来洪水和污染物迁移等环境问题,也给下水道系统不完善或不完善的低高架道路带来了环境问题。土壤是一种天然的多孔材料,其透水性会随着地面人行道的修建而被阻断,因此透水混凝土成为解决雨水径流问题的重要选择。在这项研究中,在配制混凝土拌合物时使用了重量百分比恒定为 15%的丙烯酸聚合物(AcP)水溶液,从而提高了 PC 的强度。另一种添加剂是粉煤灰 (FA),以 5%、10%、15% 和 20% 的比例部分取代 I 类水泥,从而提高 PC 的强度。对物理(孔隙率和渗透性)和机械(压缩和弯曲强度)性能进行了研究,并使用统计工具单向方差分析(ANOVA)对结果进行了分析。20% 的替代物获得了最高的抗压强度(9.89 兆帕),而 15% 的替代物获得了最高的抗折强度(3.57 兆帕)。在渗透性方面,对照组混合物(0% 粉煤灰)的性能最高,为 4.76 厘米/秒。透水混凝土的良好结果证明,在水泥中掺入丙烯酸聚合物和粉煤灰是一种有用的成分,可进一步提高其机械性能,并提高其用于缓解洪水和污染物迁移的可接受性。
{"title":"Effect of Blending Constant Concentration of Acrylic Polymer with Varying Amount of Fly Ash to the Permeability and Strength of Large Aggregate Pervious Concrete","authors":"Hermie M. Del Pilar, Carlo B. Caballero, Mike Edson T. Milano, Nikko San C. Quimio","doi":"10.4028/p-eckdy1","DOIUrl":"https://doi.org/10.4028/p-eckdy1","url":null,"abstract":"Storm water runoff brings environmental problems like flooding and pollutant transport, not only to the residential areas but also in low elevated roads with poor to bad sewage system. Soil is a naturally porous material, and its permeable property is blocked as surface pavements are constructed, making pervious concrete an important alternative in addressing the problem caused by storm water runoff. In this study, a constant weight percentage of 15% acrylic polymer (AcP) solution on water is used for the preparation of concrete mix, resulted to an increase in strength of the PC. Another additive which is the Fly ash (FA) was used to enhance the strength of the PC partially replacing the Type I cement at 5%, 10%, 15%, and 20%. Physical (porosity and permeability) and mechanical (compression and flexural strength) properties were investigated, and the statistical tool One-Way Analysis of Variance (ANOVA) was used to analyze the results. The 20% replacement obtained the highest compressive strength at 9.89MPa, while the 15% replacement acquired the highest flexural strength at 3.57 MPa. In terms of permeability, the control mix (0% Fly ash) has the highest performance at 4.76 cm/s. The favorable result in pervious concrete proved that the use of Acrylic Polymer and fly ash blend to the cement were a useful component to further improve its mechanical properties, and acceptability of its use for flood and contaminant transport mitigation.","PeriodicalId":507742,"journal":{"name":"Materials Science Forum","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141825224","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
ZnO Deposited on Natural Rubber Films by Different Coating Methods 用不同镀膜方法在天然橡胶薄膜上沉积氧化锌
Pub Date : 2024-07-18 DOI: 10.4028/p-owd6ws
Noottiyaporn Suwantrakit, P. Sujaridworakun, O. Boondamnoen
This study was focused on the incorporation of ZnO on natural rubber (NR) films using acrylic as a binder. Firstly, the dispersion of ZnO was prepared by dispersing ZnO into a mixture of acrylic emulsion and sodium cocoyl isethionate (SCI). The concentrations of acrylic emulsion were observed at 0.1 % and 0.5 %w/v while the ratio of ZnO:SCI was fixed at 1:0.25. The result shows higher concentration of acrylic emulsion could provide higher dispersion stability compared to the lower concentration. Subsequently, NR films were coated with ZnO through two-pot and one-pot methods. It was found that the surface of NR film from two-pot method (2P_film) presented uneven distribution of the ZnO while plate structure of ZnO and acrylic were observed on films surfaces one-pot method (1P0.1_film and 1P0.5_film). The Zn content on 2P_film surfaces observed by EDS was found at 14 % while 1P0.1_film and 1P0.5_film contain at 28 % and 19 %, respectively, due to higher concentration acrylic emulsion results a greater polymer network anchoring on the ZnO. The reductions of antibacterial of 2P_film, 1P0.1_film and 1P0.5_film are similar results at over 99%. It reveals that the low content of ZnO could sufficiently achieve an excellent antibacterial performance. Nevertheless, the lower concentration of ZnO/Acrylic will be conducted in further study.
本研究的重点是以丙烯酸为粘合剂在天然橡胶(NR)薄膜上掺入氧化锌。首先,将氧化锌分散到丙烯酸乳液和椰油酰异硫酸钠(SCI)的混合物中,制备氧化锌分散液。丙烯酸乳液的浓度分别为 0.1 % 和 0.5 %w/v,而氧化锌与 SCI 的比例固定为 1:0.25。结果表明,与低浓度相比,高浓度的丙烯酸乳液具有更高的分散稳定性。随后,通过二锅法和一锅法将氧化锌涂覆在 NR 薄膜上。结果发现,双锅法制备的 NR 薄膜(2P_film)表面 ZnO 分布不均匀,而单锅法制备的薄膜(1P0.1_film 和 1P0.5_film)表面 ZnO 和丙烯酸呈板状结构。通过 EDS 观察发现,2P_薄膜表面的 Zn 含量为 14%,而 1P0.1_film 和 1P0.5_film 的 Zn 含量分别为 28% 和 19%,这是因为丙烯酸乳液的浓度较高,导致 ZnO 上的聚合物网络锚定较大。2P_film 、1P0.1_film 和 1P0.5_film 的抗菌率降低幅度相似,都超过 99%。这表明,低浓度的氧化锌足以实现优异的抗菌性能。不过,我们还将进一步研究更低浓度的 ZnO/丙烯酸。
{"title":"ZnO Deposited on Natural Rubber Films by Different Coating Methods","authors":"Noottiyaporn Suwantrakit, P. Sujaridworakun, O. Boondamnoen","doi":"10.4028/p-owd6ws","DOIUrl":"https://doi.org/10.4028/p-owd6ws","url":null,"abstract":"This study was focused on the incorporation of ZnO on natural rubber (NR) films using acrylic as a binder. Firstly, the dispersion of ZnO was prepared by dispersing ZnO into a mixture of acrylic emulsion and sodium cocoyl isethionate (SCI). The concentrations of acrylic emulsion were observed at 0.1 % and 0.5 %w/v while the ratio of ZnO:SCI was fixed at 1:0.25. The result shows higher concentration of acrylic emulsion could provide higher dispersion stability compared to the lower concentration. Subsequently, NR films were coated with ZnO through two-pot and one-pot methods. It was found that the surface of NR film from two-pot method (2P_film) presented uneven distribution of the ZnO while plate structure of ZnO and acrylic were observed on films surfaces one-pot method (1P0.1_film and 1P0.5_film). The Zn content on 2P_film surfaces observed by EDS was found at 14 % while 1P0.1_film and 1P0.5_film contain at 28 % and 19 %, respectively, due to higher concentration acrylic emulsion results a greater polymer network anchoring on the ZnO. The reductions of antibacterial of 2P_film, 1P0.1_film and 1P0.5_film are similar results at over 99%. It reveals that the low content of ZnO could sufficiently achieve an excellent antibacterial performance. Nevertheless, the lower concentration of ZnO/Acrylic will be conducted in further study.","PeriodicalId":507742,"journal":{"name":"Materials Science Forum","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141826448","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Materials Science Forum
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1