土耳其西北部铅锌矿区尾矿和土壤中的重金属及健康风险评估

Mehmet Parlak, T. Tunçay, A. ÖZASLAN PARLAK
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摘要

对土耳其西北部铅锌矿区(Balya 和 Koru)采矿废物和尾矿管理不当的研究不够充分。因此,对巴利亚和科鲁的矿山尾矿和土壤中的重金属浓度进行了测定,并对重金属造成的健康风险进行了评估。Balya 矿山尾矿中的镉、铬、铜、锰、镍、铅和锌的平均浓度分别为 35.2、17.8、354.7、1735、10、10089 和 3730 毫克/千克,而 Koru 尾矿中的这些值分别为 9.9、8.9、101.5、1308、4.5、1871 和 1375 毫克/千克。在 Balya 和 Koru 采集的土壤样本中,重金属的浓度被确定为较低。对重金属健康风险的评估是根据非致癌和致癌效应进行的。成人和儿童摄入重金属的主要途径是口服。对于儿童和成人来说,Balya 和 Koru 矿山尾矿和土壤中重金属的致癌效应顺序为镉 > 铅 > 镍 > 铬。由于 Balya 矿区尾矿和土壤中的镉和铅对成人和儿童的致癌风险值高于限值,Koru 矿区尾矿和土壤中的镉对儿童的致癌风险值也高于限值。由于 Balya 和 Koru 的矿区靠近居民点,因此对人类健康构成了风险。
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Heavy metals in tailings and soils in the Pb-Zn mining areas of North-west Türkiye and health risk evaluations
Improper mining waste and tailing management in Pb-Zn mining areas (Balya and Koru) in the north-west Türkiye have not been researched sufficiently. Accordingly, concentrations of heavy metal were determined in mine tailing and soils taken from Balya and Koru, and a health risk evaluation caused by heavy metals was performed. Average Cd, Cr, Cu, Mn, Ni, Pb, and Zn concentrations in mine tailings in Balya are 35.2, 17.8, 354.7, 1735, 10, 10089, 3730 mg kg-1 and these values were determined as 9.9, 8.9, 101.5, 1308, 4.5, 1871, 1375 mg kg-1 in the tailings in Koru, respectively. The concentrations of heavy metals in the soil samples taken from both Balya and Koru were determined to be lower. The evaluation of heavy metals’ health risks was performed according to both non-carcinogenic and carcinogenic effects. The primary route of heavy metals in adults and children has been determined by oral intake. For both children and adults, the order of the carcinogenic effects of heavy metals in mine tailings and soils in Balya and Koru was Cd > Pb > Ni > Cr. As the carcinogenic risk values of Cd and Pb for adults and children in mine tailing and soils in Balya were above the limit value, the children’s Cd carcinogenic risk values were found above the limit value in mine tailing and soils in Koru. The mining area in both Balya and Koru poses a risk to human health since it is close to settlements.
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