功能梯度硬质合金的合成、特性和应用

IF 9.1 2区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Progress in Solid State Chemistry Pub Date : 2024-06-01 DOI:10.1016/j.progsolidstchem.2024.100454
Kunlong Cai , Jialin Sun , Haibin Wang , Rui Bao , Zhixing Guo , Weibin Zhang , Le Zhao , Xiao Li , Ruijun Cao , Xialun Yun , Jun Zhao
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引用次数: 0

摘要

在过去的 100 年中,硬质合金因其卓越的性能而得到了广泛的应用。尽管具有这些优势,但最近人们开始关注与传统硬质合金相关的挑战,即性能(硬度和韧性、强度和耐磨性)之间的冲突以及使用可靠性的不稳定性,因此有必要开发功能梯度硬质合金(FGCC)。尽管近几十年来,对 FGCC 的研究呈现爆炸式增长,但仍缺乏对 FGCC 的全面综述。本研究旨在总结过去 60 年间 FGCC 的发展历程,强调特定应用对具有定制性能和定制要求的 FGCC 的需求。我们首先介绍了对 FGCC 的基本认知,然后全面阐释了渗碳、脱碳、氮化、脱氮、渗透过程的梯度形成机理和构建方法(固相烧结、石墨烯掺杂和添加剂制造等),最后总结了 FGCC 的加工工艺和力学性能。此外,还讨论了添加剂对进一步提高 FGCC 性能的影响。随后,提出了 FGCC 在不同领域的可能应用。最后,本文总结了结论和最先进 FGCC 的潜在发展方向。
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Synthesis, properties, and applications of functionally gradient cemented carbides

Cemented carbides have enjoyed widespread applications as a function of their outstanding properties during the past 100 years. Despite the advantages, however, recently there have been concerns about the challenges associated with traditional cemented carbides, i.e. the conflict of properties (hardness and toughness, strength and wear resistance) as well as the instability of reliability in service, necessitating the development of functional gradient cemented carbides (FGCCs). Although recent decades, investigations have seen explosive growth in FGCCs, there is still a lack of comprehensive review on FGCCs. Herein, the current study applies towards summarize the progress of FGCCs during the past 60 years, emphasizing the demand in FGCCs with tailored properties and customized requirements for specific applications. We initially introduce basic cognition of FGCCs, subsequently, comprehensively elucidate the gradient formation mechanisms of carburization, decarburization, nitridation, denitrification, infiltration process, and construction methods (solid-phase sintering, graphene doping and additive manufacturing etc.), then summary processing techniques and mechanical properties of FGCCs. In addition, the impart of additive on further improving the properties of FGCCs is discussed. Afterward, the possible applications of FGCCs at different areas are proposed. At the end of this paper, a summary of concluding remarks and potential developed direction of state-of-the-art FGCCs is provided.

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来源期刊
Progress in Solid State Chemistry
Progress in Solid State Chemistry 化学-无机化学与核化学
CiteScore
14.10
自引率
3.30%
发文量
12
期刊介绍: Progress in Solid State Chemistry offers critical reviews and specialized articles written by leading experts in the field, providing a comprehensive view of solid-state chemistry. It addresses the challenge of dispersed literature by offering up-to-date assessments of research progress and recent developments. Emphasis is placed on the relationship between physical properties and structural chemistry, particularly imperfections like vacancies and dislocations. The reviews published in Progress in Solid State Chemistry emphasize critical evaluation of the field, along with indications of current problems and future directions. Papers are not intended to be bibliographic in nature but rather to inform a broad range of readers in an inherently multidisciplinary field by providing expert treatises oriented both towards specialists in different areas of the solid state and towards nonspecialists. The authorship is international, and the subject matter will be of interest to chemists, materials scientists, physicists, metallurgists, crystallographers, ceramists, and engineers interested in the solid state.
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