PAN/HPMC/Gr 纳米复合材料的水处理性能

Masar A. Akaood, Iftikhar M. Ali, Basma I. Waisi
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摘要

本研究探讨了利用电纺丝技术制备的聚丙烯腈:羟丙基甲基纤维素(PAN:HPMC)和聚丙烯腈:羟丙基甲基纤维素:石墨烯(Gr)复合纳米纤维。电纺丝是一种简单而多用途的技术,它依靠表面电荷之间的静电斥力从粘弹性流体中不断牵引纳米纤维。膜技术因其操作简便、效率高而在清除污染物方面发挥着重要作用。扫描电子显微镜、傅立叶变换红外光谱(FTIR)和 X 射线衍射(XRD)测量结果表明,PAN:HPMC 纳米纤维膜中成功加入了 Gr。Gr 含量对直径、孔隙率和孔径有显著影响。PAN:HPMC:0.02Gr 电纺纳米纤维膜实现了出色的油排斥(72.47%)和良好的渗透通量(750 LMH);这可能是 PAN:HPMC 纳米纤维中平均分布的 Gr 的官能团与油相互作用的结果。我们注意到,随着 Gr 含量的增加,排油量也大幅下降。这可能是因为孔隙变宽,一些锗在纳米纤维上堆积或聚集。
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Water Treatment Performance of PAN/HPMC/Gr Nano Composites
This study investigates polyacrylonitrile:hydroxypropyl methylcellulose )PAN:HPMC( and PAN:HPMC: graphene (Gr) composite nanofibers prepared using the electrospinning technique. Electrospinning is a simple and versatile technique that relies on the electrostatic repulsion between surface charges to continuously draw nanofibers from a viscoelastic fluid. Membrane technology is vital in removing contaminants due to its easy handling and high efficiency. The results demonstrated that the Gr was successfully incorporated into the PAN:HPMC nanofiber membranes, as confirmed by scanning electron microscopy, Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD) measurements. The Gr content has a significant impact on the diameter, porosity, and pore size. The PAN:HPMC:0.02Gr electrospun nanofiber membranes achieved excellent oil rejection (72.47%) and good permeability flux (750 LMH); this might be a result of how well the functional groups of the equally distributed Gr within the PAN:HPMC nanofibers interacted with oil. It was noticed that oil rejection dropped a lot as the Gr content went up. This is likely because the pores got wider and some of the Gr stacked or agglomerated across the nanofibers.  
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