以哈萨克斯坦石油公司为例修改降蜡预测模型

D. Ismailova, D. Delikesheva, A. Baibekova, A. Ismailov, G.Zh. Smailova, A.Kh. Syzdykov
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摘要

目前,哈萨克斯坦的石油和天然气部门正面临着石蜡沉积这样一个问题。与石蜡沉积和结晶相关的问题造成了大规模的困难,而预测蜡沉淀的模型仅限于特定类型的石油,因此有必要对其进行改进。本文作者分析并开发了哈萨克斯坦油田原油石蜡沉积预测模型。这项工作以 Lira-Galeana 等人的研究为基础,该研究考虑了石油混合物中不溶性固体的多组分沉积--多固体模型。研究发现,Lira-Galeana 模型使用了状态方程、各组分的挥发性和活性系数。在系统的高压下考虑了波因定效应。在实验研究中,从两个油田采集了油样。在实验室条件下测定了油的成分组成、油的倾点和流动性损失以及熔点温度。通过实验估算了油中的石蜡淤泥量。所得结果与分析溶液完全一致。在实验室测试过程中发现,在相同条件下,第二油田的石油比第一油田的石油更重,石蜡的结晶程度也更明显。利用这一预测模型,作者能够根据环境温度的变化,预测一年中原油的固体析出量。
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WAX PRECIPITATION PREDICTIVE MODEL MODIFICATION ON THE EXAMPLE OF A KAZAKHSTAN OIL
Currently, the oil and gas segment of Kazakhstan is facing such a problem as paraffin deposits. The problem associated with the deposition and crystallization of paraffin causes large-scale difficulties, and models for predicting wax precipitation are limited to specific types of oil, and therefore there is a need to improve them. The authors of this article analyzed and developed a predictive model of paraffin deposition from crude oil for Kazakhstani fields. The work is based on the study of Lira-Galeana et al., which considers the multicomponent deposition of immiscible solids from an oil mixture - a multi-solid model. During the study, it was found out that the Lira-Galeana model uses the equation of state, the volatility properties of the components and the activity coefficient. The Poynting effect was considered at high pressures in the system. For experimental studies, oil samples were taken from two fields. The component composition of the oil, the pour point and loss of fluidity of the oil, as well as the melting point temperatures were determined in laboratory conditions. The amount of paraffin sludge from the oil was estimated experimentally. The results obtained are fully consistent with the analytical solution. During laboratory tests, it was found that the oil from the second field was heavier, and the degree of crystallization of paraffin was more significant than that of oil from the first field under the same conditions. Using this predictive model, the authors were able to predict the amount of solid precipitation from crude oil during the year, depending on changes in ambient temperature.
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