使用 UiO-66/rGO 改性电极电化学测定水溶液中的沙丁胺醇

IF 1.3 Q3 CHEMISTRY, MULTIDISCIPLINARY Vietnam Journal of Chemistry Pub Date : 2024-02-14 DOI:10.1002/vjch.202300189
Le Thi Thanh Nhi, Le Thi Hoa, Dam To Uyen, Le Hoang Sinh, D. Nguyen, Ta Ngoc Bach, Tran Thanh Tam Toan, Dinh Quang Khieu
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引用次数: 0

摘要

UiO-66/rGO 材料的合成涉及将 UiO-66 与还原型氧化石墨烯 (rGO) 结合在一起。通过用 UiO-66/rGO 对玻碳电极 (GCE) 进行改性,这种复合材料被应用于沙丁胺醇 (SAL) 的电化学测定。所选技术为差分脉冲伏安法,其线性范围宽达 1-160 微米,检出限低至 0.84 微米。为确保电极的可靠性,对灵敏度、可重复性、再现性和稳定性等各个方面都进行了细致的研究。在分析猪尿液中的 SAL(n = 3)时,该电极表现出良好的回收率。值得注意的是,该方法得到的结果与使用超高效液相色谱法(UPLC)得到的结果有很好的相关性。
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Electrochemical determination of salbutamol in aqueous solutions with UiO‐66/rGO‐modified electrodes
The synthesis of the UiO‐66/rGO material involved combining UiO‐66 with reduced graphene oxide (rGO). This resulting composite found application in the electrochemical determination of salbutamol (SAL) through modification of a glassy‐carbon electrode (GCE) with UiO‐66/rGO. Differential pulse voltammetry served as the chosen technique, offering a wide linear range spanning 1–160 µm and demonstrating a low limit of detection at 0.84 µm. To ensure the reliability of the electrode, various aspects such as sensitivity, repeatability, reproducibility, and stability were meticulously studied. When applied to the analysis of SAL in swine urine solutions (n = 3), the electrode exhibited good recovery rates. Remarkably, the results obtained through this method correlated well with those acquired using ultra‐high performance liquid chromatography (UPLC).
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来源期刊
Vietnam Journal of Chemistry
Vietnam Journal of Chemistry CHEMISTRY, MULTIDISCIPLINARY-
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1.70
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