Anna Marinopoulou, Vasiliki Christopoulou, Olga Karabinaki, Dimitris Christofilos, John Arvanitidis
{"title":"利用拉曼光谱研究反式肉桂酸晶体的高压响应","authors":"Anna Marinopoulou, Vasiliki Christopoulou, Olga Karabinaki, Dimitris Christofilos, John Arvanitidis","doi":"10.1002/appl.202300129","DOIUrl":null,"url":null,"abstract":"<p>The pressure response of crystalline <i>trans</i>-cinnamic acid is studied by means of Raman spectroscopy up to 6 GPa. Pressure application causes the reversible shift of all the observed Raman peaks to higher frequencies and changes in their relative intensities, with the intermolecular vibrational modes being by far more sensitive to pressurization compared to the intramolecular ones. The present high-pressure Raman data indicate the structural stability of the <i>trans</i>-cinnamic acid crystal and molecular conformation up to the highest pressure attained in the experiments, the importance of the hydrogen bonding, as well as the considerable strengthening of the intermolecular interactions at elevated pressures.</p>","PeriodicalId":100109,"journal":{"name":"Applied Research","volume":"3 4","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/appl.202300129","citationCount":"0","resultStr":"{\"title\":\"The high-pressure response of trans-cinnamic acid crystals studied by Raman spectroscopy\",\"authors\":\"Anna Marinopoulou, Vasiliki Christopoulou, Olga Karabinaki, Dimitris Christofilos, John Arvanitidis\",\"doi\":\"10.1002/appl.202300129\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The pressure response of crystalline <i>trans</i>-cinnamic acid is studied by means of Raman spectroscopy up to 6 GPa. Pressure application causes the reversible shift of all the observed Raman peaks to higher frequencies and changes in their relative intensities, with the intermolecular vibrational modes being by far more sensitive to pressurization compared to the intramolecular ones. The present high-pressure Raman data indicate the structural stability of the <i>trans</i>-cinnamic acid crystal and molecular conformation up to the highest pressure attained in the experiments, the importance of the hydrogen bonding, as well as the considerable strengthening of the intermolecular interactions at elevated pressures.</p>\",\"PeriodicalId\":100109,\"journal\":{\"name\":\"Applied Research\",\"volume\":\"3 4\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-01-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/appl.202300129\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Research\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/appl.202300129\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Research","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/appl.202300129","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The high-pressure response of trans-cinnamic acid crystals studied by Raman spectroscopy
The pressure response of crystalline trans-cinnamic acid is studied by means of Raman spectroscopy up to 6 GPa. Pressure application causes the reversible shift of all the observed Raman peaks to higher frequencies and changes in their relative intensities, with the intermolecular vibrational modes being by far more sensitive to pressurization compared to the intramolecular ones. The present high-pressure Raman data indicate the structural stability of the trans-cinnamic acid crystal and molecular conformation up to the highest pressure attained in the experiments, the importance of the hydrogen bonding, as well as the considerable strengthening of the intermolecular interactions at elevated pressures.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
