在碳布上智能构建用于增强超级电容器和锂离子电池的 Fe2O3 纳米线阵列

Xiangyu Yin, Zhen Liu, Xinyi Li, Meili Qi, Ming Hu, Xin Mu
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摘要

由于具有出色的理论比容量,过渡金属氧化物 Fe2O3 因其作为阴极材料的潜力而备受关注。然而,Fe2O3 仍然存在导电率低和在充放电过程中体积膨胀大的缺点。在本实验中,我们报道了一种通过水热法在碳布(Fe2O3@CC)上生长 Fe2O3 纳米线阵列的简便策略。制备的 Fe2O3@CC 复合材料可用作 LIB 和超级电容器的电极。在此,我们利用上述支撑在碳布上的独特的 Fe2O3@CC 纳米线阵列复合材料作为具有高比表面积的重复性和定向性阳极电极复合材料。在电流密度为 200 mA g-1 时,超级电容器在循环 500 次后显示出 221.19 F g-1 的比电容。将 Fe2O3@CC 纳米线复合材料用于 LIB 中,在 500 mA g-1 的高电流密度下显示出 240.7 mAh g-1 的超高速率容量,以及在 100 mA g-1 下循环 100 次后 514.1 mAh g-1 的高可逆容量。
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Smart construction of Fe2O3 nanowire arrays on carbon cloth for enhanced supercapacitor and lithium-ion battery
Due to its excellent theoretical specific capacity, the transition metal oxide Fe2O3 has garnered significant attention due to its potential as a cathode material. Nevertheless, Fe2O3 remains the drawback of low the electrical conductivity and significant volume expansion in the charge and discharge process. In this experiment, we have reported a facile strategy for Fe2O3 nanowire array grown on carbon cloth (Fe2O3@CC) by hydrothermal method. The prepared Fe2O3@CC composite was served as an electrode for LIBs and supercapacitors. Herein, we utilized above-mentioned unique composite of Fe2O3@CC nanowire array supported on carbon cloth as repetitive and directional composite of anode electrode composite with high specific surface area. The supercapacitors exhibited a specific capacitance of 221.19 F g−1 after 500 cycles at a current density of 200 mA g−1. Fe2O3@CC nanowire composite was utilized in LIBs, demonstrating exceptional rate capacity of 240.7 mAh g−1 at a high current density of 500 mA g−1, as well as a high reversible capacity of 514.1 mAh g−1 after 100 cycles at 100 mA g−1.
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