基于尖扫描可见近红外光谱仪构建预测茯苓粉水分含量的可持续模型

IF 1.8 Q2 AGRICULTURE, MULTIDISCIPLINARY Open Agriculture Pub Date : 2024-01-01 DOI:10.1515/opag-2022-0268
H. Z. Amanah, Sri Rahayoe, Eni Harmayani, Reza Adhitama Putra Hernanda, Khoirunnisaa, Ajeng Siti Rohmat, Hoonsoo Lee
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引用次数: 0

摘要

茯苓粉(PP)的水分含量是一个固有的质量参数。因此,有几种分析方法(如烘箱干燥和卡尔-费歇尔滴定法)被用来测定其含量。然而,这些技术都存在各种缺点,如耗时长、需要制备样品、劳动密集型、产生化学废物等。本研究旨在探讨可见近红外光谱(Vis-NIR)作为一种无损且可持续的分析技术预测聚丙烯中水分含量的潜力。在这项研究中,我们开发了一种传统的机器学习算法--偏最小二乘回归(PLSR),并将其与两个光谱波段(可见近红外(400-1,000 nm)和近红外(954-1,700 nm))相结合。为了提高 PLSR 的性能,我们采用了七种预处理技术:平均值归一化、最大值归一化、范围归一化、乘法散度校正、标准正态变异(SNV)以及 Savitzky-Golay 一阶和二阶导数。我们发现,使用近红外光谱波段的 PLSR 更为有效;预处理后的平均归一化效果最佳,使用五个潜变量的判定系数(R p 2 )为 0.96,标准误差预测值(SEP)为 0.56。此外,我们还通过 SNV 预处理近红外光谱,利用投影中的变量重要性提取了 39 个最佳波长,并取得了更好的性能(R p 2 {R}_{p}^{2} = 0.95,SEP = 0.56%wb,5 个 LV)。
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Construction of a sustainable model to predict the moisture content of porang powder (Amorphophallus oncophyllus) based on pointed-scan visible near-infrared spectroscopy
The moisture content of porang powder (PP) is an inherent quality parameter. Therefore, several analytical methods, such as oven drying and Karl–Fischer titration, were applied to determine the content. However, these techniques are noted to have various disadvantages, such as being time-consuming, requiring sample preparation, being labor-intensive, and producing chemical waste. This study aims to investigate the potential of visible near-infrared (Vis-NIR) spectroscopy as a nondestructive and sustainable analytical technology to predict moisture content in PP. In this study, we developed a traditional machine learning algorithm, a partial least squares regression (PLSR), in tandem with two spectral bands, which are Vis-NIR (400–1,000 nm) and NIR (954–1,700 nm). To upgrade the performance of PLSR, we applied seven preprocessing techniques: mean normalization, maximum normalization, range normalization, multiplicative scatter correction, standard normal variate (SNV), and Savitzky–Golay first and second derivatives. We found that PLSR using NIR spectral bands was more effective; the preprocessed mean normalization exhibited the best results with a coefficient of determination ( R p 2 ) \left({R}_{p}^{2}) of 0.96 and a standard error prediction (SEP) of 0.56 using five latent variables. Furthermore, we also extracted 39 optimum wavelengths using variable importance in projection and achieved better performance ( R p 2 {R}_{p}^{2} = 0.95, SEP = 0.56%wb, and 5 LVs) via SNV preprocessed NIR spectra.
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来源期刊
Open Agriculture
Open Agriculture AGRICULTURE, MULTIDISCIPLINARY-
CiteScore
3.80
自引率
4.30%
发文量
61
审稿时长
9 weeks
期刊介绍: Open Agriculture is an open access journal that publishes original articles reflecting the latest achievements on agro-ecology, soil science, plant science, horticulture, forestry, wood technology, zootechnics and veterinary medicine, entomology, aquaculture, hydrology, food science, agricultural economics, agricultural engineering, climate-based agriculture, amelioration, social sciences in agriculuture, smart farming technologies, farm management.
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